Safety of 1-(4-Nitrophenyl)ethanone. In 2020.0 INORG CHEM published article about FRUSTRATED LEWIS PAIRS; ION-PAIRS; ACTIVATION; AL(C6F5)(3); ARYLATION; ACIDITY in [Ould, Darren M. C.; Carden, Jamie L.; Page, Rowan; Melen, Rebecca L.] Cardiff Univ, Sch Chem, Cardiff Catalysis Inst, Cardiff CF10 3AT, Wales in 2020.0, Cited 28.0. The Name is 1-(4-Nitrophenyl)ethanone. Through research, I have a further understanding and discovery of 100-19-6.
The addition of the Grignard 3,4,5-(ArMgBr)-Mg-F to aluminum(III) chloride in ether generates the novel triarylalane Al(3,4,5-Ar-F)(3)center dot OEt2. Attempts to synthesize this alane via transmetalation from the parent borane with trimethylaluminum gave a dimeric structure with bridging methyl groups, a product of partial transmetalation. On the other hand, the novel alane Al(2,3,(4)-Ar-F)(3) was synthesized from the parent borane and trimethylaluminum. Interestingly, the solid-state structure of Al(2,3,4-Ar-F)(3) shows an extended chain structure resulting from neighboring Al-F contacts. Al(3,4,5-Ar-F)(3)center dot OEt2 was then found to be an effective catalyst for the hydroboration of carbonyls, imines, and alkynes with pinacolborane.
Safety of 1-(4-Nitrophenyl)ethanone. About 1-(4-Nitrophenyl)ethanone, If you have any questions, you can contact Ould, DMC; Carden, JL; Page, R; Melen, RL or concate me.
Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem