Recommanded Product: 1-(4-Nitrophenyl)ethanone. In 2020.0 J MOL STRUCT published article about C-S BOND; X-RAY-STRUCTURE; DENSITY-FUNCTIONAL THEORY; ELECTROCHEMICAL PROPERTIES; IRIDIUM(III) COMPLEX; EXCITATION-ENERGIES; LIGANDS SYNTHESIS; CLEAVAGE; THIOETHER; THIOLATO in [Roy, Puspendu; Manna, Chandan Kumar; Mondal, Tapan Kumar] Jadavpur Univ, Dept Chem, Kolkata 700032, India; [Sarkar, Deblina] Bagnan Coll, Dept Chem, Howrah 711303, WB, India; [Ghosh, Paramita; Murmu, Nabendu] Chittaranjan Natl Canc Inst, Dept Signal Transduct & Biogenis Amines, Kolkata 700026, India; [Roy, Puspendu] Univ Calcutta, Netaji Nagar Day Coll, Dept Chem, Kolkata 700092, India in 2020.0, Cited 44.0. The Name is 1-(4-Nitrophenyl)ethanone. Through research, I have a further understanding and discovery of 100-19-6.
A new fluorescent Rh(III) cyclometalated complex, [Rh(PPh3)(2)(L)Cl] (1) is synthesized via sp(2)(C)-S bond activation of a thioether containing azo-phenol ligand (L-SCH2CH3). The pseudo octahedral geometry around rhodium is confirmed by single crystal X-ray diffraction method. Cyclic voltammogram of the complex exhibits a quasi-reversible oxidation couple with E-1/2 of 0.74 V (Delta E = 100 mV) along with a quasi-reversible reduction couple (E-1/2 = -1.18 V, Delta E = 130 mV) in acetonitrile. The complex exhibits low energy emission band at 682 nm with emission quantum yield (phi = 0.103) upon excitation at 583 nm. Cytotoxicity of the complex is studied by MTT method with human breast cancer cell lines and IC50 value is found to 18.5 mu M. In presence of the complex (10 mu M) a bright red fluorescence image of MCF-7 cell lines is observed under fluorescence microscope. Moreover, the complex acts as effective catalyst towards transfer hydrogenation of ketones. (C) 2019 Elsevier B.V. All rights reserved.
Recommanded Product: 1-(4-Nitrophenyl)ethanone. Welcome to talk about 100-19-6, If you have any questions, you can contact Roy, P; Sarkar, D; Ghosh, P; Manna, CK; Murmu, N; Mondal, TK or send Email.
Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem