Formula: C8H7NO3. In 2021.0 NEW J CHEM published article about ASYMMETRIC TRANSFER HYDROGENATION; TRANSITION-METAL-COMPLEXES; MAGNETIC-PROPERTIES; AMINOPHOSPHONATES; DERIVATIVES; SPECTROSCOPY; CYTOTOXICITY; RHENIUM; DIPHOSPHINE; 2-PROPANOL in [Hkiri, Shaima; Semeril, David] Univ Strasbourg, UMR CNRS 7177, Synth Organometall & Catalyse, 4 Rue Blaise Pascal, F-67008 Strasbourg, France; [Hkiri, Shaima; Touil, Soufiane; Samarat, Ali] Univ Carthage, Fac Sci Bizerte, Lab Heteroorgan Cpds & Nanostruct Mat, LR18ES11, Bizerte 7021, Tunisia; [Gourlaouen, Christophe] Univ Strasbourg, Lab Chim Quant, UMR CNRS 7177, 4 Rue Blaise Pascal, F-67008 Strasbourg, France in 2021.0, Cited 71.0. The Name is 1-(4-Nitrophenyl)ethanone. Through research, I have a further understanding and discovery of 100-19-6.
Three alpha-aminophosphonates, namely diethyl[(5-phenyl-1,3,4-oxadiazol-2-ylamino)(4-trifluoromethylphenyl) methyl]phosphonate (3a), diethyl[(5-phenyl-1,3,4-oxadiazol-2-ylamino)(2-methoxyphenyl)methyl]phosphonate (3b) and diethyl[(5-phenyl-1,3,4-oxadiazol-2-ylamino)(4-nitrophenyl)methyl]phosphonate (3c), were synthetized via the Pudovik-type reaction between diethyl phosphite and imines, obtained from 5-phenyl-1,2,4-oxadiazol-2-amine and aromatic aldehydes, under microwave irradiation. Compounds 3a-c underwent complexation with a ruthenium(ii) precursor, selectively at the more basic nitrogen atom of the oxadiazole ring, leading to the corresponding ruthenium complexes 4a-c of the formula [RuCl2(L)(p-cymene)] (L = alpha-aminophosphonates 3a-c). Complexes 4a-c proved to be efficient catalysts for the transfer hydrogenation of ketones to alcohols. All new compounds were fully characterised by elemental analysis, infrared, mass and NMR spectroscopy. An X-ray structure of the alpha-aminophosphonate 3b was obtained and revealed the presence, in the solid state, of an infinite chain of 3b units supramolecularly interlinked. Two X-ray diffraction studies carried out on ruthenium complexes confirm the specific coordination of the electron-enricher nitrogen atom of the oxadiazole ring.
About 1-(4-Nitrophenyl)ethanone, If you have any questions, you can contact Hkiri, S; Gourlaouen, C; Touil, S; Samarat, A; Semeril, D or concate me.. Formula: C8H7NO3
Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem