An article Rapid and Atom Economic Synthesis of Isoquinolines and Isoquinolinones by C-H/N-N Activation Using a Homogeneous Recyclable Ruthenium Catalyst in PEG Media WOS:000471298500005 published article about H BOND ACTIVATION; SUPERCRITICAL CARBON-DIOXIDE; DIRECTING GROUP; O BOND; INTERNAL OXIDANT; POLYETHYLENE-GLYCOL; IONIC LIQUIDS; EFFICIENT SYNTHESIS; IRIDIUM COMPLEXES; ORGANIC-SYNTHESIS in [Deshmukh, Dewal S.; Gangwar, Neha; Bhanage, Bhalchandra M.] Inst Chem Technol, Dept Chem, Mumbai 400019, Maharashtra, India in 2019.0, Cited 164.0. The Name is 1-(4-Nitrophenyl)ethanone. Through research, I have a further understanding and discovery of 100-19-6. Computed Properties of C8H7NO3
Herein, we report an atom-efficient, rapid, green, and sustainable approach to synthesize isoquinolines and isoquinolinones using a homogeneous recyclable ruthenium catalyst in PEG Media assisted by microwave energy. Dibenzoylhydrazine was used for C-H/N-N activation reactions for the first time in combination with ketazine as oxidizing directing groups for annulation reactions with internal alkynes. The developed protocol is environmentally benign due to significantly shortened times with an easy extraction method, higher atom economy, external oxidant and silver or antimony salt free conditions, applicability to a gram scale synthesis, use of biodegradable solvent and wide substrate scope with higher product yields. Moreover, it is worth noting that the established methodology allowed reuse of the catalytic system for up to five successive runs with minimal loss in activity.
Welcome to talk about 100-19-6, If you have any questions, you can contact Deshmukh, DS; Gangwar, N; Bhanage, BM or send Email.. Computed Properties of C8H7NO3
Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem