An article Metal-ligand cooperativity in a ruthenium(II) complex of bis-azoaromatic ligand for catalytic dehydrogenation of alcohols WOS:000447787500022 published article about TRANSFER HYDROGENATION; ELECTRONIC-STRUCTURES; OXIDATION; ACTIVATION; REDUCTION; MOLECULES; CHEMISTRY; EFFICIENT; ENERGIES; METHANOL in [Saha, Tanushri; Pramanick, Rajib; Sengupta, Debabrata; Goswami, Sreebrata] Indian Assoc Cultivat Sci, Sch Chem Sci, Kolkata 700032, India in 2019.0, Cited 46.0. COA of Formula: C8H7NO3. The Name is 1-(4-Nitrophenyl)ethanone. Through research, I have a further understanding and discovery of 100-19-6
Herein a new Ru-phosphine complex (1) with molecular formula [RuL(PPh3)Cl-2] is reported where L is a redox active pincer ligand 2,6-bis(phenylazo)pyridine. The isolated complex has been characterized by usual spectroscopic techniques including single crystal X-ray crystallographic analysis. Complex 1 efficiently catalyzes aerobic oxidation of a wide range of primary and secondary benzylic, allylic, heterocyclic, alicyclic alcohols under mild conditions and is found to be superior over several other Ru (0, +2 and + 3), Ru-H and Ru-PPh3 catalysts. Mechanistic studies indicate that a transient Ru-H intermediate is formed in the catalytic cycle which gets switched into a Ru-hydrazo intermediate via hydrogen-walking mechanism. The catalyst is regenerated by aerial oxidation producing H2O2 as a by-product.
Welcome to talk about 100-19-6, If you have any questions, you can contact Saha, T; Pramanick, R; Sengupta, D; Goswami, S or send Email.. COA of Formula: C8H7NO3
Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem