Application In Synthesis of 1-(4-Nitrophenyl)ethanone. Recently I am researching about ASYMMETRIC TRANSFER HYDROGENATION; CHIRAL PRIMARY AMINES; ALKYL-ARYL KETONES; FORMIC-ACID; STEREOSELECTIVE HYDROGENATION; MECHANISTIC ASPECTS; CARBONYL-COMPOUNDS; HYDRIDE COMPLEXES; AROMATIC KETONES; C-13 NMR, Saw an article supported by the JSPS KAKENHIMinistry of Education, Culture, Sports, Science and Technology, Japan (MEXT)Japan Society for the Promotion of ScienceGrants-in-Aid for Scientific Research (KAKENHI) [JP18K19070]. Published in AMER CHEMICAL SOC in WASHINGTON ,Authors: Tanaka, K; Miki, T; Murata, K; Yamaguchi, A; Kayaki, Y; Kuwata, S; Ikariya, T; Watanabe, M. The CAS is 100-19-6. Through research, I have a further understanding and discovery of 1-(4-Nitrophenyl)ethanone
Cp*Ir complexes bearing a 2-picolinamide moiety serve as effective catalysts for the direct reductive amination of ketonic compounds to give primary amines under transfer hydrogenation conditions using ammonium formate as both the nitrogen and hydrogen source. The clean and operationally simple transformation proceeds with a substrate to catalyst molar ratio (S/C) of up to 20,000 at relatively low temperature and exhibits excellent chemoselectivity toward primary amines.
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Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem