Chemistry is traditionally divided into organic and inorganic chemistry. Computed Properties of C10H10O3, The former is the study of compounds containing at least one carbon-hydrogen bonds.In a patent£¬Which mentioned a new discovery about 2879-20-1
Iron-catalyzed C[sbnd]C bond activation/C[sbnd]O bond formation: Direct conversion of ketones to esters
The iron-catalyzed oxidative activation of the (O)C[sbnd]C bond in ketones has been developed. This method enables direct synthesis of esters by the reaction between ketones and alcohols via conversion of the (O)C[sbnd]C bond to the (O)C[sbnd]O bond. The reaction runs selectively: the (O)C[sbnd]CAlkyl bond is activated, while the (O)C[sbnd]CAryl bond remains intact (i.e., iron-catalyzed intermolecular anti-Baeyer-Villiger activation of the (O)C[sbnd]C bond). The reaction conditions are carefully optimized and allow the production of esters with yields of up to 95%. The method is based on the inexpensive and commercially available catalyst (FeCl3), oxidant ((NH4)2S2O8), and solvent (DCE) without using any ligands or additives.
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Reference£º
Benzodioxan,
1,4-Benzodioxane | C8H8O2 – PubChem