The chemical properties of alicyclic heterocycles are similar to those of the corresponding chain compounds. Compound: 5,5′-Dimethyl-2,2′-bipyridine, is researched, Molecular C12H12N2, CAS is 1762-34-1, about Dynamic Helicates Self-Assembly from Homo- and Heterotopic Dynamic Covalent Ligand Strands, the main research direction is transition metal schiff base helicate complex preparation self assembly; crystal structure transition metal schiff base helicate; double-helical structures; dynamic covalent chemistry; metallo-supramolecular structures; programmed self-assembly.Computed Properties of C12H12N2.
The understanding and the application of reversible covalent reactions and coordination chem. together with the proper design of the mol. frameworks, allow to achieve not only well-defined output architectures but also different grades of complex behavior. In this work, the dynamic nature of the helical systems offers an addnl. level of complexity by combining self-sorting on two levels: (1) the build-up of the ligand strand constituents from their components through dynamic covalent chem.; (2) the assembly of the helicates from the ligands and the metal cations through dynamic metallo-supramol. chem. The information encoded in the ligands constituent mol. was read differently (and accurately at the same time) by metal cations that varied in the coordination algorithms. It enabled the selective formation of a specific type of helicates from a wide library of helicates formed by the possible combination of subcomponents. Ligands containing dynamic tridentate and/or bidentate binding motifs in the same strand were studied to explore the helicates self-assembly with appropriate metal cations.
In addition to the literature in the link below, there is a lot of literature about this compound(5,5′-Dimethyl-2,2′-bipyridine)Computed Properties of C12H12N2, illustrating the importance and wide applicability of this compound(1762-34-1).