Synthetic Route of C12H12N2. The mechanism of aromatic electrophilic substitution of aromatic heterocycles is consistent with that of benzene. Compound: 5,5′-Dimethyl-2,2′-bipyridine, is researched, Molecular C12H12N2, CAS is 1762-34-1, about Syntheses, molecular structures, and spectroscopic properties of manganese(II)/(III) complexes with tetraphenylimidodiphosphinato and bi-pyridine or salicylaldehyde ligands. Author is Qian, Zhe; Zhang, Ying; Jia, Ai-Quan; Shi, Hua-Tian; Zhang, Qian-Feng.
Treatment of [Mn(CH3COO)2·4H2O] with two equivalent of K[N(Ph2PO)2] in the presence of one equivalent of 2,2′-bipyridine (bpy) or 5,5′-dimethyl-2,2′-bipyridine(dmbpy) in ethanol gave the mono-nuclear manganese(II) complexes [Mn{η1-O-N(Ph2PO)2}{N(Ph2PO)2}(EtOH)(bpy)] (1) and [Mn{N(Ph2PO)2}2(dmbpy)] (2), resp. Interaction of [Mn(CH3COO)2·4H2O], K[N(Ph2PO)2] and salicylaldehyde or 5-chlorosalicylaldehyde or 3,5-dibromosalicylaldehyde in the presence of triethylamine in methanol gave the bi-nuclear manganese(II) complexes [Mn2{N(Ph2PO)2}2(μ,η2-O,O’-Sal)2(MeOH)2] (3) and [Mn2{N(Ph2PO)2}2(μ,η2-O,O’-5-Cl-Sal)2(MeOH)2] (4), and a tetra-nuclear manganese(II)/(III) complex [Mn4{N(Ph2PO)2}2(μ,η2-O,O’-3,5-Br2-Sal’)2(MeOH)4(μ-OMe)2(μ3-OMe)2] (5), resp. All complexes were characterized by IR and UV spectroscopy, their mol. structures were unambiguously established by single crystal x-ray diffraction. The electrochem. properties of complexes 1-5 were also studied.
Compound(1762-34-1)Synthetic Route of C12H12N2 received a lot of attention, and I have introduced some compounds in other articles, similar to this compound(5,5′-Dimethyl-2,2′-bipyridine), if you are interested, you can check out my other related articles.