So far, in addition to halogen atoms, other non-metallic atoms can become part of the aromatic heterocycle, and the target ring system is still aromatic.Duan, Jicheng; Wang, Yuquan; Qi, Liangliang; Guo, Peng; Pang, Xiaobo; Shu, Xing-Zhong researched the compound: 5,5′-Dimethyl-2,2′-bipyridine( cas:1762-34-1 ).Recommanded Product: 5,5′-Dimethyl-2,2′-bipyridine.They published the article 《Nickel-Catalyzed Cross-Electrophile C(sp3)-Si Coupling of Unactivated Alkyl Bromides with Vinyl Chlorosilanes》 about this compound( cas:1762-34-1 ) in Organic Letters. Keywords: nickel catalyst cross coupling alkyl bromide vinyl chloro silane; alkyl silane organosilane preparation. We’ll tell you more about this compound (cas:1762-34-1).
Cross-electrophile C-Si coupling has emerged as a promising tool for the construction of organosilanes, but the potential of this method remains largely unexplored. Herein, we report a C(sp3)-Si coupling of unactivated alkyl bromides with vinyl chlorosilanes. The reaction proceeds under mild conditions, and it offers a new approach to alkylsilanes. Functionalities such as Grignard-sensitive groups (e.g., acid, amide, alc., ketone, and ester), acid-sensitive groups (e.g., ketal and THP protection), alkyl fluoride and chloride, aryl bromide, alkyl tosylate and mesylate, silyl ether, and amine were tolerated. Incorporation of the -Si(vinyl)R2 moiety into complex mols. and the immobilization of a glass surface by formed organosilanes were demonstrated.
From this literature《Nickel-Catalyzed Cross-Electrophile C(sp3)-Si Coupling of Unactivated Alkyl Bromides with Vinyl Chlorosilanes》,we know some information about this compound(1762-34-1)Recommanded Product: 5,5′-Dimethyl-2,2′-bipyridine, but this is not all information, there are many literatures related to this compound(1762-34-1).