Recently I am researching about ASYMMETRIC HYDROGENATION; IRON; EFFICIENT; MECHANISM; CHEMISTRY; ALDEHYDES; NITRILES; ALCOHOLS; LIGANDS; METALS, Saw an article supported by the Russian Science FoundationRussian Science Foundation (RSF) [17-73-20144]; Ministry of Science and Higher Education of the Russian Federation. Published in WILEY-V C H VERLAG GMBH in WEINHEIM ,Authors: Shvydkiy, NV; Vyhiyskyi, O; Nelyubina, YV; Perekalin, DS. The CAS is 100-19-6. Through research, I have a further understanding and discovery of 1-(4-Nitrophenyl)ethanone. COA of Formula: C8H7NO3
Catalytic hydrogenation is one of the most important reactions both in academic research and industry. We explored ability of the manganese pi-complexes to act as Shvo-type catalysts for transfer hydrogenation of ketones. DFT calculations suggested that the transfer of hydrogen atoms from the hypothetical intermediate [(C6Me3H2OH)Mn(CO)(2)H] to acetone has low activation barrier of 10.9 kcal mol(-1). Experimentally a number of ketones with various functional groups (OMe, NH2, Cl, CF3, pyridyl) were successfully reduced in isopropanol at 90 degrees C in the presence of the complex[(C6Me3H2OH)Mn(CO)(3)]BF4 (1 mol %) and (BuOK)-Bu-t (75 mol %). However, further investigation revealed that the reduction was mainly promoted by base rather than the manganese complex.
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Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem