SDS of cas: 100-19-6. In 2019.0 POLYHEDRON published article about ASYMMETRIC TRANSFER HYDROGENATION; SCHIFF-BASE LIGAND; EFFECTIVE CORE POTENTIALS; DENSITY-FUNCTIONAL THEORY; MOLECULAR CALCULATIONS; EXCITATION-ENERGIES; CARBON-SULFUR; RUTHENIUM(II); ACTIVATION; SULFINATO in [Roy, Puspendu; Manna, Chandan Kumar; Naskar, Rahul; Mondal, Tapan Kumar] Jadavpur Univ, Dept Chem, Kolkata 700032, India; [Roy, Puspendu] Univ Calcutta, Dept Chem, Netaji Nagar Day Coll, Kolkata 700092, India in 2019.0, Cited 49.0. The Name is 1-(4-Nitrophenyl)ethanone. Through research, I have a further understanding and discovery of 100-19-6.
A new rhodium(III) triphenylphosphine complex having the general formula [Rh(PPh3)(2)(L)Cl] (1) was synthesized by C-S bond cleavage of an ONS donor azo-thioether ligand (L-CH2Ph). The complex was thoroughly characterized by various spectroscopic techniques. Its single crystal X-ray structure exhibits an octahedral geometry around the rhodium(III) center. A cyclic voltammogram of the complex exhibits ligand based quasi-irreversible oxidative and reductive responses. The electronic structure, redox properties and electronic excitations in the complex were interpreted by DFT and TDDFT calculations. The complex effectively catalyzed the transfer hydrogenation reaction of ketones with high yields in i-PrOH in the presence of a base. (C) 2018 Elsevier Ltd. All rights reserved.
SDS of cas: 100-19-6. Welcome to talk about 100-19-6, If you have any questions, you can contact Roy, P; Manna, CK; Naskar, R; Mondal, TK or send Email.
Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem