An article Scissoring Enaminone C=C Double Bond by Free Radical Process for the Synthesis of alpha-Trifluoromethyl Ketones with CF3SO2Na WOS:000606840200105 published article about METAL-FREE SYNTHESIS; FACILE SYNTHESIS; OXIDATIVE TRIFLUOROMETHYLATION; MEDIATED TRIFLUOROMETHYLATION; ENOL ACETATES; CF3 RADICALS; CLEAVAGE; FLUORINATION; MIGRATION; CATALYSIS in [Gan, Lu; Yu, Qing; Liu, Yunyun; Wan, Jie-Ping] Jiangxi Normal Univ, Coll Chem & Chem Engn, Nanchang 330022, Jiangxi, Peoples R China; [Gan, Lu] Nanchang Inst Technol, Sch Sci, Nanchang 330029, Jiangxi, Peoples R China in 2021.0, Cited 66.0. The Name is 1-(4-Nitrophenyl)ethanone. Through research, I have a further understanding and discovery of 100-19-6. HPLC of Formula: C8H7NO3
The C=C double bond cleavage on tertiary enaminones, enabling the formation of a new C-CF3 bond, has been realized as a practical method for the synthesis of alpha-trifluoromethyl ketones with only the promotion of TBHP and ambient heating. Control experiments support that the reactions proceed via a featured free radical process. The deuterium labeling experiment employing D2O indicates that water participated in the product formation by donating the hydrogen atom for the newly generated alpha-C-H bond in the product.
HPLC of Formula: C8H7NO3. Welcome to talk about 100-19-6, If you have any questions, you can contact Gan, L; Yu, Q; Liu, YY; Wan, JP or send Email.
Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem