An article Copper-Catalyzed [2+2+1+1] Annulation for the Regioselective Synthesis of 2,6-Diarylpyridines via C1-Insertion and Subsequent Cyclization WOS:000563958600033 published article about METAL-FREE SYNTHESIS; ONE-POT SYNTHESIS; CROSS-COUPLING REACTIONS; C BOND-CLEAVAGE; POLYSUBSTITUTED PYRIDINES; SUBSTITUTED PYRIDINES; PUMMERER REACTION; OXIME ACETATES; STRATEGY; QUINOLINES in [Vodnala, Nagaraju; Gujjarappa, Raghuram; Kaldhi, Dhananjaya; Kabi, Arup K.; Malakar, Chandi C.] Natl Inst Technol Manipur, Dept Chem, Imphal 795004, Manipur, India; [Satheesh, Vanaparthi] Technion Israel Inst Technol, Schulich Fac Chem, IL-3200003 Haifa, Israel; [Gupta, Richa] Natl Univ Singapore, Dept Chem, Singapore 117543, Singapore in 2020.0, Cited 89.0. Formula: C8H7NO3. The Name is 1-(4-Nitrophenyl)ethanone. Through research, I have a further understanding and discovery of 100-19-6
Copper-catalyzed [2+2+1+1] annulation strategy has been investigated for the regioselective synthesis of symmetrical and unsymmetrical 2,6-diarylpyridines using aliphatic amines as nitrogen source and DMSO as C1-synthon. The developed protocol was successful for the transformation of non-activated aromatic ketones and non-activated aliphatic amines into 2,6-diarylpyridinesviaan easy to access approach. This protocol has been verified on wide range of substrates having various functional groups.
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Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem