I found the field of Chemistry very interesting. Saw the article Cobalt(II)porphyrin-Mediated Selective Synthesis of 1,5-Diketones via an Interrupted-Borrowing Hydrogen Strategy Using Methanol as a C1 Source published in 2021.0. Application In Synthesis of 1-(4-Nitrophenyl)ethanone, Reprint Addresses Venkatasubbaiah, K (corresponding author), Natl Inst Sci Educ & Res NISER, Sch Chem Sci, Bhubaneswar 752050, Odisha, India.; Chandrasekhar, V (corresponding author), Tata Inst Fundamental Res Hyderabad, Hyderabad 500046, Telangana, India.; Chandrasekhar, V (corresponding author), Indian Inst Technol Kanpur, Dept Chem, Kanpur 208016, Uttar Pradesh, India.. The CAS is 100-19-6. Through research, I have a further understanding and discovery of 1-(4-Nitrophenyl)ethanone
A novel cobalt(II)porphyrin-mediated acceptorless dehydrogenation of methanol is reported for the first time. This methodology has been applied for the coupling of a variety of ketones with methanol to produce 1,5-diketones along with H-2 and H2O as the environment friendly byproducts. This paradigm was also demonstrated for a one-pot synthesis of substituted pyridines using a sequential addition protocol where the 1,5-diketones were generated in situ. From many experiments including those involving deuterium labeling, it is proposed that protonated cobalt(II)-porphyrin methoxide complex acts as an intermediate to generate formaldehyde along with a metal hydride.
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Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem