Formula: C8H7NO3. Recently I am researching about MANGANESE-DIOXIDE OXIDATION; HIGHER ALPHA-OLEFINS; METHYL KETONES; REGIOSELECTIVE OXIDATION; ASYMMETRIC ALLYLATION; AROMATIC-COMPOUNDS; SYSTEM; CONVENIENT; PRINCIPLES; DISCOVERY, Saw an article supported by the SERB New DelhiDepartment of Science & Technology (India)Science Engineering Research Board (SERB), India [EMR/2017/000499]; CSIR New Delhi, IndiaCouncil of Scientific & Industrial Research (CSIR) – India. Published in ROYAL SOC CHEMISTRY in CAMBRIDGE ,Authors: Fernandes, RA; Ramakrishna, GV; Bethi, V. The CAS is 100-19-6. Through research, I have a further understanding and discovery of 1-(4-Nitrophenyl)ethanone
Efficient and mild reaction conditions for Wacker-type oxidation of terminal olefins of less explored homoallyl alcohols to beta-hydroxy-methyl ketones have been developed by using a Pd(ii) catalyst and MnO(2)as a co-oxidant. The method involves mild reaction conditions and shows good functional group compatibility along with high regio- and chemoselectivity. While our earlier system of PdCl2/CrO3/HCl produced alpha,beta-unsaturated ketones from homoallyl alcohols, the present method provided orthogonally the beta-hydroxy-methyl ketones. No overoxidation or elimination of benzylic and/or beta-hydroxy groups was observed. The method could be extended to the oxidation of simple terminal olefins as well, to methyl ketones, displaying its versatility. An application to the regioselective synthesis of gingerol is demonstrated.
About 1-(4-Nitrophenyl)ethanone, If you have any questions, you can contact Fernandes, RA; Ramakrishna, GV; Bethi, V or concate me.. Formula: C8H7NO3
Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem