I found the field of Chemistry very interesting. Saw the article [eta(5)-Cp*B-Mes](+): A Masked Potent Boron Lewis Acid published in 2019.0. SDS of cas: 100-19-6, Reprint Addresses Chiu, CW (corresponding author), Natl Taiwan Univ, Dept Chem, 1,Sect 4,Roosevelt Rd, Taipei 10617, Taiwan.. The CAS is 100-19-6. Through research, I have a further understanding and discovery of 1-(4-Nitrophenyl)ethanone
The chemistry of the boron cation has been revitalized in the past decade due to its newfound application in stoichiometric and catalytic organic reactions. To extend the frontier of boron cation catalysis, we came to discover that a mesityl-substituted eta(5)-Cp*-coordinated boron cation could serve as a powerful Lewis acid for organic catalytic transformations. The boron cation [Cp*B-Mes][B(C6F5)(4)] ([1] [B(C6F5)(4)]) stabilized in a boronium-like electronic structure binds to Et3PO readily and displays an acceptor number exceeding that of B(C6F5)(3) on the Gutmann-Beckett acidity scale. The steric and electronic stabilization exerted by the electron-donating Cp* renders the highly Lewis acidic boron cation an easy-to-handle catalyst for hydrodeoxygenation of aryl ketones at ambient temperature. The exceptional catalytic performance of [1](+) implies that the incorporation of a coordinatively flexible substituent at boron is critical in bringing catalytic activity and stability to boron cation catalysts.
Welcome to talk about 100-19-6, If you have any questions, you can contact Tseng, HC; Shen, CT; Matsumoto, K; Shih, DN; Liu, YH; Peng, SM; Yamaguchi, S; Lin, YF; Chiu, CW or send Email.. SDS of cas: 100-19-6
Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem