Recently I am researching about MAGNESIUM-CATALYZED HYDROBORATION; ASYMMETRIC TRANSFER HYDROGENATION; ABUNDANT METAL-CATALYSTS; IRON; ALKYNES; REDUCTION; HYDROSILYLATION; ALKYLATION; MECHANISM; NITRILES, Saw an article supported by the American Chemical Society Petroleum Research FundAmerican Chemical Society [S4247-UNI3]; PSC-CUNY awards [69069-0047, 60328-0048]; Seed grant from the Office for Advancement of Research; PRISM program at John Jay College, CUNY; National Science FoundationNational Science Foundation (NSF) [CHE-1464543]. Published in AMER CHEMICAL SOC in WASHINGTON ,Authors: Zeng, HS; Wu, J; Li, SH; Hui, C; Ta, A; Cheng, SY; Zheng, SP; Zhang, GQ. The CAS is 100-19-6. Through research, I have a further understanding and discovery of 1-(4-Nitrophenyl)ethanone. SDS of cas: 100-19-6
A novel nonanuclear copper(II) complex obtained by a facile one-pot self-assembly was found to catalyze the hydroboration of ketones and aldehydes with the absence of an activator under mild, solvent-free conditions. The catalyst is air-and moisture-stable, displaying high efficiency (1980 h(-1) turnover frequency, TOF) and chemo-selectivity on aldehydes over ketones and ketones over imines. This represents a rare example of divalent copper catalyst for the hydroboration of carbonyls.
SDS of cas: 100-19-6. Welcome to talk about 100-19-6, If you have any questions, you can contact Zeng, HS; Wu, J; Li, SH; Hui, C; Ta, A; Cheng, SY; Zheng, SP; Zhang, GQ or send Email.
Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem