I found the field of Chemistry; Science & Technology – Other Topics very interesting. Saw the article Heterogeneous carbon nitride photocatalyst for C-C bond oxidative cleavage of vicinal diols in aerobic micellar medium published in 2020.0. Safety of 1-(4-Nitrophenyl)ethanone, Reprint Addresses Niu, TF; Ni, BQ (corresponding author), Jiangnan Univ, Sch Chem & Mat Engn, Wuxi, Jiangsu, Peoples R China.. The CAS is 100-19-6. Through research, I have a further understanding and discovery of 1-(4-Nitrophenyl)ethanone
A green and efficient visible-light promoted aerobic oxidative C-C bond cleavage of vicinal diols in micellar medium has been developed. This protocol used graphitic carbon nitride with nitrogen vacancies (CN620) as a metal-free recyclable photocatalyst and CTAB as surfactant in water. Control experiments and the ESR results indicated that superoxide radicals and valence band holes played an important role in the reaction. Further isotope experiments suggested both a beta-scission/HAT pathway and an oxidation/hydrolysis/dehydration pathway for the reaction, which is different from previous reports. The semiconductor/micellar catalyst system can be recycled at least 10 times without a significant reduction in activity. Furthermore, this reaction could be carried out under solar light irradiation and was applicable to large-scale reactions with similar results.
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Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem