Recently I am researching about INTRAMOLECULAR CARBOSULFENYLATION; ASYMMETRIC BROMOLACTONIZATION; CHLOROCYCLIZATION; CONSTRUCTION; ALKENES; DIHALOGENATION; HALOFUNCTIONALIZATION; BROMOETHERIFICATION; SULFENOAMINATION; HALOGENATION, Saw an article supported by the One Thousand Youth Talents Program of China; National Natural Science Foundation of ChinaNational Natural Science Foundation of China (NSFC) [21772239]; Natural Science Foundation of Guangdong ProvinceNational Natural Science Foundation of Guangdong Province [2014A030312018]. Published in WILEY-V C H VERLAG GMBH in WEINHEIM ,Authors: Cao, QX; Luo, J; Zhao, XD. The CAS is 86-29-3. Through research, I have a further understanding and discovery of 2,2-Diphenylacetonitrile. SDS of cas: 86-29-3
An unprecendented chiral sulfide catalyzed desymmetrizing enantioselective chlorination is disclosed. Various aryl-tethered diolefins and diaryl-tethered olefins afforded teralins and tricyclic hexahydrophenalene derivatives, respectively, bearing multiple stereogenic centers in high yields with excellent enantio- and diastereoselectivities. In contrast, the tertiary amine catalyst (DHQD)(2)PHAL led to a diastereomeric product. The products could be transformed into a variety of compounds, such as spiro-N-heterocycles.
SDS of cas: 86-29-3. About 2,2-Diphenylacetonitrile, If you have any questions, you can contact Cao, QX; Luo, J; Zhao, XD or concate me.
Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem