Zhang, DX; Zhou, XW; Liu, RX; Li, MQ; Li, XY; Jiang, R; Nie, HF; Zhang, SY in [Zhang, Dongxu; Zhang, Shengyong] Northwest A&F Univ, Coll Chem & Pharm, Shaanxi Key Lab Nat Prod & Chem Biol, Yangling 712100, Shaanxi, Peoples R China; [Liu, Ruixia; Li, Muqiong; Li, Xiaoye; Jiang, Ru; Nie, Huifang] Fourth Mil Med Univ, Sch Pharm, Xian 710032, Peoples R China; [Zhou, Xiaowei] 944th Hosp PLA, Jiuquan 735000, Peoples R China published Josiphos-type binaphane ligands for the asymmetric Ir-catalyzed hydrogenation of acyclic aromatic N-aryl imines in 2020.0, Cited 35.0. COA of Formula: C8H7NO3. The Name is 1-(4-Nitrophenyl)ethanone. Through research, I have a further understanding and discovery of 100-19-6.
The Ir-catalyzed asymmetric hydrogenation of acyclic aromatic N-aryl imines with Josiphos-type binaphane ligands has been described. Under the optimized conditions, a wide range of imines were hydrogenated to afford the corresponding chiral amines in high yields (up to 94%) and good to excellent enantioselectivities (up to > 99% ee). The synthetic utility of the present protocol has been demonstrated through the asymmetric synthesis of the key chiral intermediates of calcium sensing receptor modulators on a gram scale.
About 1-(4-Nitrophenyl)ethanone, If you have any questions, you can contact Zhang, DX; Zhou, XW; Liu, RX; Li, MQ; Li, XY; Jiang, R; Nie, HF; Zhang, SY or concate me.. COA of Formula: C8H7NO3
Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem