I found the field of Chemistry very interesting. Saw the article Commercially Available CuO Catalyzed Hydrogenation of Nitroarenes Using Ammonia Borane as a Hydrogen Source published in 2020.0. Application In Synthesis of 1-(4-Nitrophenyl)ethanone, Reprint Addresses Zhou, WJ (corresponding author), Univ Jinan, Inst Adv Interdisciplinary Res, Collaborat Innovat Ctr Technol & Equipment Biol D, Jinan 250022, Shandong, Peoples R China.; Wang, B (corresponding author), Univ Jinan, Sch Chem & Chem Engn, Jinan 250022, Shandong, Peoples R China.. The CAS is 100-19-6. Through research, I have a further understanding and discovery of 1-(4-Nitrophenyl)ethanone
Tandem ammonia borane dehydrogenation and nitroarenes hydrogenation has been reported as a novel strategy for the preparation of aromatic amines. However, the practical application of this strategy is subjected to the high-cost and tedious preparation of supported noble metal nanocatalysts. The commercially available CuO powder is herein demonstrated to be a robust catalyst for hydrogenation of nitroarenes using ammonia borane as a hydrogen source under mild conditions. Numerous amines (even sterically hindered, halogenated, and diamines) could be obtained through this method. This monometallic catalyst is characteristic of support-free, excellent chemoselectivity, low-cost, and high recyclability, which will favor its future utilization in preparative reduction chemistry. Mechanistic studies are also carried out to clarify that diazene and azoxybenzene are key intermediates of this heterogeneous reduction.
Application In Synthesis of 1-(4-Nitrophenyl)ethanone. About 1-(4-Nitrophenyl)ethanone, If you have any questions, you can contact Du, JL; Chen, J; Xia, HH; Zhao, YW; Wang, F; Liu, H; Zhou, WJ; Wang, B or concate me.
Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem