Schroeder, S; Strauch, C; Gaelings, N; Niggemann, M in [Schroeder, Sebastian; Strauch, Christina; Gaelings, Niklas; Niggemann, Meike] Rhein Westfal TH Aachen, Inst Organ Chem, Landoltweg 1, D-52072 Aachen, Germany published Vinyl Triflimides-A Case of Assisted Vinyl Cation Formation in 2019.0, Cited 56.0. Product Details of 100-19-6. The Name is 1-(4-Nitrophenyl)ethanone. Through research, I have a further understanding and discovery of 100-19-6.
A new concept for selectivity control in carbocation-driven reactions has been identified which allows for the chemo-, regio-, and stereoselective addition of nucleophiles to alkynes-assisted vinyl cation formation-enabled by a Li+-based supramolecular framework. Mechanistic analysis of a model complex (Li2NTf2+center dot 3H(2)O) confirms that solely the formation of a complex between the incoming nucleophile and the transition state of the alkyne protonation is responsible for the resulting selective Naddition to the vinyl cation. Into the bargain, a general, operationally simple synthetic procedure to previously inaccessible vinyl triflimides is provided.
About 1-(4-Nitrophenyl)ethanone, If you have any questions, you can contact Schroeder, S; Strauch, C; Gaelings, N; Niggemann, M or concate me.. Product Details of 100-19-6
Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem