Recommanded Product: 1762-34-1. The protonation of heteroatoms in aromatic heterocycles can be divided into two categories: lone pairs of electrons are in the aromatic ring conjugated system; and lone pairs of electrons do not participate. Compound: 5,5′-Dimethyl-2,2′-bipyridine, is researched, Molecular C12H12N2, CAS is 1762-34-1, about H/D solvent isotope effects on the photoracemization reaction of enantiomeric the tris(2,2′-bipyridine)ruthenium(II) complex and its analogues. Author is Asahara, Masahiro; Kurimoto, Haruhiko; Nakamizu, Masato; Hattori, Shingo; Shinozaki, Kazuteru.
This work assessed solvent isotope effects on the photoracemization rate and emission lifetime for [Ru(bpy)3]2+ (bpy = 2,2′-bipyridine) in water. An anal. of the effects of temperature on photoracemization rate and emission lifetime demonstrated that the transition from one enantiomer to the other is unaffected by the isotopic composition of the solvent. Also deactivation from the metal-to-ligand charge-transfer (3MLCT) excited state to the ground state is responsible for the solvent isotope effect on the photoracemization rate. The photoracemization reaction proceeds via a bond-breaking mechanism. In this process, a five-coordinated species produced through breaking of the Ru-N bond in the 3d-d* state undergoes a structural change to produce an achiral five-coordinated species. An anal. of the effect of temperature on emission lifetime, excluding the activation to the 3d-d* state that leads to the structural change, showed that the solvent isotopic composition affects deactivation from the 4th MLCT state.
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