An article Bronsted Acid-Initiated Formal [1,3]-Rearrangement Dictated by beta-Substituted Ene-Aldimines WOS:000474795200015 published article about AMINO-ACIDS; REARRANGEMENT in [Jongwohan, Chanantida; Suzuki, Toshiyasu; Fujinami, Takeshi; Adachi, Kiyohiro; Momiyama, Norie] Inst Mol Sci, Okazaki, Aichi 4448787, Japan; [Jongwohan, Chanantida; Suzuki, Toshiyasu; Momiyama, Norie] SOKENDAI Grad Univ Adv Studies, Okazaki, Aichi 4448787, Japan; [Honda, Yasushi] HPC Syst Inc, West Japan Off, Shimogyo Ku, 646 Nijohanjikicho, Kyoto 6008412, Japan; [Adachi, Kiyohiro] Univ Tokyo, Sch Engn, Dept Appl Chem, Bunkyo Ku, 7-3-1 Hongo, Tokyo 1118656, Japan in 2019, Cited 18. The Name is 2,2-Diphenylacetonitrile. Through research, I have a further understanding and discovery of 86-29-3. Safety of 2,2-Diphenylacetonitrile
The rearrangement of ene-aldimines is a useful reaction for affording homoallylic amines. Despite their utilities in synthetic chemistry, the rearrangement for accessing homoallylic amines substituted at the 2-position remains elusive. In this study, the Bronsted acid-initiated formal [1,3]-rearrangement of ene-aldimines was developed to synthesize 2,4,4-substituted homoallylic amines that were otherwise inaccessible previously. Our study reveals an intermolecular pathway in which the rearrangement proceeds via a protonation-mediated 2-azaallenium cation.
Safety of 2,2-Diphenylacetonitrile. Welcome to talk about 86-29-3, If you have any questions, you can contact Jongwohan, C; Honda, Y; Suzuki, T; Fujinami, T; Adachi, K; Momiyama, N or send Email.
Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem