Day: November 23, 2021

Akasapu, K; Ojah, N; Gupta, AK; Choudhury, AJ; Mishra, P in [Akasapu, Kumudhini; Gupta, Arun Kumar; Mishra, Poonam] Tezpur Univ, Dept Food Engn & Technol, Tezpur 784028, Assam, India; [Ojah, Namita; Choudhury, Arup Jyoti] Tezpur Univ, Dept Phys, Tezpur 784028, Assam, India published An innovative approach for iron fortification of rice using cold plasma in 2020, Cited 24. Formula: C14H11N. The Name is 2,2-Diphenylacetonitrile. Through research, I have a further understanding and discovery of 86-29-3.

In the present study, an innovative cold plasma treatment was used as a tool to fortify the white rice. The amounts of ferrous sulphate and ascorbic acid were optimized for improving the bioavailability of iron. White rice samples were treated with plasma at a constant voltage of 20 kV for varying time (10 min and 15 min). The exposure time of plasma was selected based on the surface characteristics, hydrophilicity and thermal properties. Significant improvement was observed in the characteristics of hydrophilicity, surface energy, cooking time and hardness of plasma-treated rice. Plasma treated rice was fortified with the optimum concentrations of iron and ascorbic acid solution. Optimum concentrations of iron and ascorbic acid per 100 g of rice (862.93 mg and 1398.27 mg) were found by conducing experiments using Central Composite Design of Response Surface Methodology. Further, rice was blended with untreated rice in the ratio of 1:100 and 1:200 and was packed in LDPE and PP pouches and was stored at ambient temperature for further storage analysis. The in vitro bioavailability of iron was significantly higher in the plasma-treated fortified rice at both 1.35 and 7.5 pH than in the control sample, and plasma treatment significantly reduced the rate of oxidation of iron during storage.

About 2,2-Diphenylacetonitrile, If you have any questions, you can contact Akasapu, K; Ojah, N; Gupta, AK; Choudhury, AJ; Mishra, P or concate me.. Formula: C14H11N

Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem

Zhao, LW; Zheng, K; Tong, JY; Jin, JZ; Shen, C in [Zhao, Linwei] Changzhou Univ, Coll Petr Chem Ind, Changzhou 213164, Peoples R China; [Zheng, Kai; Tong, Jianying; Jin, Jianzhong; Shen, Chao] Zhejiang Shuren Univ, Coll Biol & Environm Engn, Hangzhou 310015, Zhejiang, Peoples R China published Novel Biomass-Derived Fe3O4@Pd NPs as Efficient and Sustainable Nanocatalyst for Nitroarene Reduction in Aqueous Media in 2019, Cited 27. Recommanded Product: 100-19-6. The Name is 1-(4-Nitrophenyl)ethanone. Through research, I have a further understanding and discovery of 100-19-6.

A novel magnetically recyclable nitrogen-doped Fe3O4@Pd NPs was prepared from the biomass-based materials which was employed as carbon and nitrogen source. The as-prepared catalysts were fully characterized by a variety of physicochemical techniques and were exploited for nitroaromatic hydrogenation with broad scope and excellent chemoselectivity using molecular hydrogen as a reductant. The heterogeneous catalysts can be recovered easily and reused for at least eight recycling reactions without obviously loss of catalytic properties. In addition, using this protocol, the key intermediate of marketed drug Osimertinib could be synthesized easily.Graphical A [GRAPHICS]

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Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem

An article Continuous-Flow Hydrogenation and Reductive Deuteration of Nitriles: a Simple Access to alpha,alpha-Dideutero Amines WOS:000486789800001 published article about D EXCHANGE-REACTIONS; SELECTIVE DEUTERATION; SODIUM-BOROHYDRIDE; ISOTOPIC EXCHANGE; CARBOXYLIC-ACID; DEUTERIUM; EFFICIENT; RHODIUM; HETEROCYCLES; MECHANISM in [Meszaros, Rebeka; Peng, Bai-Jing; Otvos, Sandor B.; Fulop, Ferenc] Univ Szeged, Inst Pharmaceut Chem, Eotvos U 6, H-6720 Szeged, Hungary; [Peng, Bai-Jing; Yang, Shyh-Chyun] Kaohsiung Med Univ, Sch Pharm, Coll Pharm, Kaohsiung 807, Taiwan; [Otvos, Sandor B.; Fulop, Ferenc] Hungarian Acad Sci, MTA SZTE Stereochem Res Grp, Eotvos U 6, H-6720 Szeged, Hungary; [Otvos, Sandor B.] Graz Univ, NAWI Graz, Inst Chem, Heinrichstr 28, A-8010 Graz, Austria; [Yang, Shyh-Chyun] Kaohsiung Med Univ, Dept Fragrance & Cosmet Sci, Coll Pharm, Kaohsiung 807, Taiwan; [Yang, Shyh-Chyun] Kaohsiung Med Univ, Kaohsiung Med Univ Hosp, Dept Med Res, Kaohsiung 807, Taiwan in 2019, Cited 61. Safety of 2,2-Diphenylacetonitrile. The Name is 2,2-Diphenylacetonitrile. Through research, I have a further understanding and discovery of 86-29-3

A simple and efficient continuous flow methodology has been developed for hydrogenation and reductive deuteration of nitriles to yield primary amines and also valuable alpha,alpha-dideutero analogues. Raney nickel proved to be a useful catalyst for the transformation of a wide range of nitriles under reasonably mild conditions with excellent deuterium incorporation (>90 %) and quantitative conversion. Among known model compounds, three new deuterated primary amines were prepared. The large-scale synthesis of deuterated tryptamine was also carried out to deliver 1.1 g product under flow conditions.

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Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem

I found the field of Chemistry very interesting. Saw the article Metal-Free Cross-Dehydrogenative C-O Coupling of Carbonyl Compounds with N-Hydroxyimides: Unexpected Selective Behavior of Highly Reactive Free Radicals at an Elevated Temperature published in 2020. Product Details of 86-29-3, Reprint Addresses Terent’ev, AO (corresponding author), Russian Acad Sci, ND Zelinsky Inst Organ Chem, 47 Leninsky Prosp, Moscow 119991, Russia.. The CAS is 86-29-3. Through research, I have a further understanding and discovery of 2,2-Diphenylacetonitrile

Cross-dehydrogenative C-O coupling of N-hydroxyimides with ketones, esters, and carboxylic acids was achieved employing the di-tertbutyl peroxide as a source of free radicals and a dehydrogenating agent. The proposed method is experimentally simple and demonstrates the outstanding efficiency for the challenging CH substrates, such as unactivated esters and carboxylic acids. It was shown that N-hydroxyphthalimide drastically affects the oxidative properties of t-BuOOt-Bu by intercepting the t-BuO center dot radicals with the formation of phthalimide-N-oxyl radicals, a species responsible for both hydrogen atom abstraction from the CH reagent and the selective formation of the C-O coupling product by selective radical cross-recombination. The practical applicability of the developed method was exemplified by the single-stage synthesis of commercial reagent (known as Baran aminating reagent precursor) from isobutyric acid and N-hydroxysuccinimide, whereas in the standard synthetic approach, four stages are necessary.

Welcome to talk about 86-29-3, If you have any questions, you can contact Krylov, IB; Lopat’eva, ER; Budnikov, AS; Nikishin, GI; Terent’ev, AO or send Email.. Product Details of 86-29-3

Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem

Authors Deshmukh, DS; Bhanage, BM in GEORG THIEME VERLAG KG published article about H ACTIVATION; POLYETHYLENE-GLYCOL; ORGANIC-SYNTHESIS; INTERNAL ALKYNES; DIRECTING GROUP; EFFICIENT SYNTHESIS; IRIDIUM COMPLEXES; O BOND; FUNCTIONALIZATION; RHODIUM in [Deshmukh, Dewal S.; Bhanage, Bhalchandra M.] Inst Chem Technol, Dept Chem, N Parekh Marg, Mumbai 400019, Maharashtra, India in 2019.0, Cited 112.0. SDS of cas: 100-19-6. The Name is 1-(4-Nitrophenyl)ethanone. Through research, I have a further understanding and discovery of 100-19-6

In this work, N-Cbz hydrazone has been employed as a rarely explored directing group for the synthesis of isoquinolines by annulation with internal alkynes via C-H/ N-N activation using Ru catalyst. Additive as well as external oxidant-free rapid protocol has been established for the synthesis of isoquinolines using microwave strategy. Use of non-volatile and biodegradable PEG as a green solvent with lower catalyst loading makes the proposed protocol environmentally benign. Further, higher functional group tolerance and wide substrate scope has been observed under the stated methodology with higher yields.

Welcome to talk about 100-19-6, If you have any questions, you can contact Deshmukh, DS; Bhanage, BM or send Email.. SDS of cas: 100-19-6

Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem

In 2019.0 ORG BIOMOL CHEM published article about BIOLOGICAL EVALUATION; PRIMARY AMINES; EFFICIENT; DERIVATIVES; REAGENT; INHIBITORS; CONVERSION; DISCOVERY; DESIGN; ACID in [Kale, Ashok; Medishetti, Nagaraju; Atmakur, Krishnaiah] Indian Inst Chem Technol, CSIR, Fluoro & Agro Chem Dept, Hyderabad 500007, Telangana, India; [Kanugala, Sirisha; Kumar, Ganesh C.] Indian Inst Chem Technol, CSIR, Med Chem & Pharmacol Div, Hyderabad 500007, Telangana, India; [Kale, Ashok; Medishetti, Nagaraju; Kanugala, Sirisha; Atmakur, Krishnaiah] Indian Inst Chem Technol, AcSIR, Hyderabad 500007, Telangana, India in 2019.0, Cited 48.0. The Name is 1-(4-Nitrophenyl)ethanone. Through research, I have a further understanding and discovery of 100-19-6. Recommanded Product: 1-(4-Nitrophenyl)ethanone

Reduction of various azides using Na2S has been accomplished in water, and, in situ, the resulting amines on reaction with various ketones lead to pyrazolo[3,4-b]pyridines in one pot. Thus, a number of new trifluoromethyl-substituted pyrazolo[3,4-b]pyridine compounds have been prepared and screened for antimicrobial activity against different Gram-positive and Gram-negative strains. A good number of compounds, 4a, 4b, 4d, 4f, 4i, 4k, 4l, 4m, 4r and 4s, were found to possess promising activity. Notably, Na2S on hydrolysis in water generates H2S and NaOH, which facilitate the reduction of azides followed by intramolecular cyclization leading to the title compounds. To the best of our knowledge, this is the first report of the synthesis of the title compounds in aqueous medium in a one-pot reaction.

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Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem

In 2020 ORG LETT published article about FLUOROCARBON DERIVATIVES; NITROGEN; SILVER; ACID; CONSTRUCTION; COORDINATION; HYDROCARBONS; INDOLIZINES in [Li, Qiang-Qiang; Ochiai, Kotaro; Lee, Cherie-Anne; Ito, Shingo] Nanyang Technol Univ, Sch Phys & Math Sci, Div Chem & Biol Chem, Singapore 637371, Singapore in 2020, Cited 68. The Name is 2,2-Diphenylacetonitrile. Through research, I have a further understanding and discovery of 86-29-3. COA of Formula: C14H11N

Here we report the 1,3-dipolar cycloaddition of polycyclic aromatic azomethine ylides with nitriles to produce highly fused imidazole derivatives, that is, tribenzo[b,g,ij]imidazo-[2,1,5-de]quinolizine. The advantages of this transformation are the broad substrate scope and the good functional group compatibility. The subsequent palladium-catalyzed intramolecular cyclization provides an efficient approach to further pi-extended imidazoles, that is, 14b(1),15-diazadibenzo[fg,ij]cyclopenta[rst]pentaphene.

COA of Formula: C14H11N. Welcome to talk about 86-29-3, If you have any questions, you can contact Li, QQ; Ochiai, K; Lee, CA; Ito, S or send Email.

Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem

Recently I am researching about BETA-AMINO ALCOHOLS; STEREOSELECTIVE-SYNTHESIS; DIASTEREOSELECTIVE SYNTHESIS; GEM-DIFLUOROALKENES; OXIDATIVE NITRATION; CARBONYL-COMPOUNDS; SCHENCK REACTION; EFFICIENT; CONVERSION; REDUCTION, Saw an article supported by the MEYS CR [LM2015043]. Published in ROYAL SOC CHEMISTRY in CAMBRIDGE ,Authors: Otevrel, J; Svestka, D; Bobal, P. The CAS is 86-29-3. Through research, I have a further understanding and discovery of 2,2-Diphenylacetonitrile. Quality Control of 2,2-Diphenylacetonitrile

We have identified a novel one-pot method for the synthesis of beta-amino alcohols, which is based on C-H bond hydroxylation at the benzylic alpha-carbon atom with a subsequent nitrile or amide functional group reduction. This cascade process uses molecular oxygen as an oxidant and sodium bis(2-methoxyethoxy)aluminum hydride as a reductant. The substrate scope was examined on 30 entries and, although the respective products were provided in moderate yields only, the above simple protocol may serve as a direct and powerful entry to the sterically congested 1,2-amino alcohols that are difficult to prepare by other routes. The plausible mechanistic rationale for the observed results is given and the reaction was applied to a synthesis of a potentially bioactive target.

Welcome to talk about 86-29-3, If you have any questions, you can contact Otevrel, J; Svestka, D; Bobal, P or send Email.. Quality Control of 2,2-Diphenylacetonitrile

Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem

An article Ruthenium complexes of phosphine-amide based ligands as efficient catalysts for transfer hydrogenation reactions WOS:000626650200019 published article about ASYMMETRIC TRANSFER HYDROGENATION; CARBONYL-COMPOUNDS; CRYSTAL-STRUCTURES; KETONES; REDUCTION; ALCOHOLS; METAL; ACID; CONSTANTS; ALDEHYDES in [Yadav, Samanta; Vijayan, Paranthaman; Yadav, Sunil; Gupta, Rajeev] Univ Delhi, Dept Chem, Delhi 110007, India in 2021, Cited 90. Category: benzodioxans. The Name is 1-(4-Nitrophenyl)ethanone. Through research, I have a further understanding and discovery of 100-19-6

This work presents three mononuclear Ru(ii) complexes of tridentate phosphine-carboxamide based ligands providing a NNP coordination environment. The octahedral Ru(ii) ion shows additional coordination with co-ligands; CO, Cl and CH3OH. All three Ru(ii) complexes were thoroughly characterized including their crystal structures. These Ru(ii) complexes were utilized as catalysts for the transfer hydrogenation of assorted carbonyl compounds, including some challenging biologically relevant substrates, using isopropanol as the hydrogen source. The binding studies illustrated the coordination of the isopropoxide ion by replacing a Ru-ligated chloride ion followed by the generation of the Ru-H intermediate that was isolated and characterized and was found to be involved in the catalysis.

About 1-(4-Nitrophenyl)ethanone, If you have any questions, you can contact Yadav, S; Vijayan, P; Yadav, S; Gupta, R or concate me.. Category: benzodioxans

Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem

I found the field of Chemistry very interesting. Saw the article One-pot method for the synthesis of 1-aryl-2-aminoalkanol derivatives from the corresponding amides or nitriles published in 2020. Formula: C14H11N, Reprint Addresses Otevrel, J; Bobal, P (corresponding author), Masaryk Univ, Dept Chem Drugs, Fac Pharm, Palackeho 1946-1, Brno 61242, Czech Republic.. The CAS is 86-29-3. Through research, I have a further understanding and discovery of 2,2-Diphenylacetonitrile

We have identified a novel one-pot method for the synthesis of beta-amino alcohols, which is based on C-H bond hydroxylation at the benzylic alpha-carbon atom with a subsequent nitrile or amide functional group reduction. This cascade process uses molecular oxygen as an oxidant and sodium bis(2-methoxyethoxy)aluminum hydride as a reductant. The substrate scope was examined on 30 entries and, although the respective products were provided in moderate yields only, the above simple protocol may serve as a direct and powerful entry to the sterically congested 1,2-amino alcohols that are difficult to prepare by other routes. The plausible mechanistic rationale for the observed results is given and the reaction was applied to a synthesis of a potentially bioactive target.

Welcome to talk about 86-29-3, If you have any questions, you can contact Otevrel, J; Svestka, D; Bobal, P or send Email.. Formula: C14H11N

Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem