Day: November 9, 2021

Computed Properties of C8H7NO3. Authors Wang, YZ; Huang, XL; Wang, Q; Tang, YH; Xu, SL; Li, Y in AMER CHEMICAL SOC published article about in [Wang, Yongzhuang; Huang, Xiaoli; Wang, Qin; Tang, Yuhai; Xu, Silong; Li, Yang] Xi An Jiao Tong Univ, Dept Mat Chem, Sch Chem, Xian 710049, Peoples R China; [Wang, Yongzhuang; Huang, Xiaoli; Wang, Qin; Tang, Yuhai; Xu, Silong; Li, Yang] Xi An Jiao Tong Univ, Xian Key Lab Sustainable Energy Mat Chem, Xian 710049, Peoples R China in 2021.0, Cited 61.0. The Name is 1-(4-Nitrophenyl)ethanone. Through research, I have a further understanding and discovery of 100-19-6

An efficient Cp*Rh-III-catalyzed formal C(sp(3))-H activation/spiroannulation of alkylidene Meldrum’s acids with alkynes has been developed using catalytical Cu(OAc)(2) and air as the oxidant. This reaction demonstrates a new and straightforward approach to spirocyclopentadienes with Meldrum’s acid moieties in good to excellent yields under mild reaction conditions with a broad substrate scope. Notably, this protocol provides a novel and straightforward approach to cyclopentadienes with various substitution patterns and the corresponding cyclopentadienyl-type ligands from simple substrates.

Computed Properties of C8H7NO3. Bye, fridends, I hope you can learn more about C8H7NO3, If you have any questions, you can browse other blog as well. See you lster.

Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem

Authors Cao, QX; Luo, J; Zhao, XD in WILEY-V C H VERLAG GMBH published article about INTRAMOLECULAR CARBOSULFENYLATION; ASYMMETRIC BROMOLACTONIZATION; CHLOROCYCLIZATION; CONSTRUCTION; ALKENES; DIHALOGENATION; HALOFUNCTIONALIZATION; BROMOETHERIFICATION; SULFENOAMINATION; HALOGENATION in [Cao, Qingxiang; Luo, Jie; Zhao, Xiaodan] Sun Yat Sen Univ, Sch Chem, Inst Organ Chem, Guangzhou 510275, Guangdong, Peoples R China; [Cao, Qingxiang; Luo, Jie; Zhao, Xiaodan] Sun Yat Sen Univ, Sch Chem, MOE Key Lab Bioinorgan & Synthet Chem, Guangzhou 510275, Guangdong, Peoples R China in 2019, Cited 81. Product Details of 86-29-3. The Name is 2,2-Diphenylacetonitrile. Through research, I have a further understanding and discovery of 86-29-3

An unprecendented chiral sulfide catalyzed desymmetrizing enantioselective chlorination is disclosed. Various aryl-tethered diolefins and diaryl-tethered olefins afforded teralins and tricyclic hexahydrophenalene derivatives, respectively, bearing multiple stereogenic centers in high yields with excellent enantio- and diastereoselectivities. In contrast, the tertiary amine catalyst (DHQD)(2)PHAL led to a diastereomeric product. The products could be transformed into a variety of compounds, such as spiro-N-heterocycles.

Bye, fridends, I hope you can learn more about C14H11N, If you have any questions, you can browse other blog as well. See you lster.. Product Details of 86-29-3

Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem

COA of Formula: C8H7NO3. Cai, S; Shao, NN; Chen, YY; Li, AB; Pan, J; Zhu, HJ; Zou, HB; Zeng, S; Sun, LL; Zhao, JH in [Cai, Sheng; Chen, Yuanyuan; Pan, Jie; Zeng, Su; Sun, Lianli] Zhejiang Univ, Coll Pharmaceut Sci, Inst Drug Metab & Pharmaceut Anal, Hangzhou 310058, Zhejiang, Peoples R China; [Shao, Nana; Zou, Hongbin] Zhejiang Univ, Coll Pharmaceut Sci, Inst Drug Discovery & Design, Hangzhou 310058, Zhejiang, Peoples R China; [Li, Anbang; Zhao, Jinhao] Zhejiang Univ, Inst Pesticide & Environm Toxicol, Minist Agr, Key Lab Mol Biol Crop Pathogens & Insects, Hangzhou 310029, Zhejiang, Peoples R China; [Zhu, Huajian] Zhejiang Univ City Coll, Sch Med, Hangzhou 310015, Zhejiang, Peoples R China published Enantioselective Reduction of alpha,beta-Unsaturated Ketones and Aryl Ketones by Perakine Reductase in 2019.0, Cited 46.0. The Name is 1-(4-Nitrophenyl)ethanone. Through research, I have a further understanding and discovery of 100-19-6.

This report describes the enantioselective reduction of structurally diverse alpha,beta-unsaturated ketones and aryl ketones by perakine reductase (PR) from Rauvolfia. This enzymatic reduction produces alpha-chiral allylic and aryl alcohols with excellent enantioselectivity and most of the products in satisfactory yields. Furthermore, the work demonstrates 1 mmol scale reactions for product delivery without any detrimental effect on yield and enantioselectivity. The catalytic mechanism, determined by 3D-structure-based modeling of PR and ligand complexes, is also described.

Welcome to talk about 100-19-6, If you have any questions, you can contact Cai, S; Shao, NN; Chen, YY; Li, AB; Pan, J; Zhu, HJ; Zou, HB; Zeng, S; Sun, LL; Zhao, JH or send Email.. COA of Formula: C8H7NO3

Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem

An article Tuneable Copper Catalysed Transfer Hydrogenation of Nitrobenzenes to Aniline or Azo Derivatives WOS:000531351500001 published article about ASYMMETRIC TRANSFER HYDROGENATION; AROMATIC NITRO-COMPOUNDS; CHEMOSELECTIVE REDUCTION; POLYANILINE NANOFIBERS; CARBONYL-COMPOUNDS; STANNOUS CHLORIDE; N-ARYLATION; NITROARENES; NANOPARTICLES; GLYCEROL in [Moran, Maria Jesus; Martina, Katia; Baricco, Francesca; Tagliapietra, Silvia; Manzoli, Maela; Cravotto, Giancarlo] Univ Turin, Dipartimento Sci & Tecnol Farmaco, Via Pietro Giuria 9, I-10125 Turin, Italy in 2020.0, Cited 63.0. The Name is 1-(4-Nitrophenyl)ethanone. Through research, I have a further understanding and discovery of 100-19-6. Computed Properties of C8H7NO3

A highly versatile and flexible copper nanoparticle (Cu(0) NPs) catalytic system has been developed for the controlled and selective transfer hydrogenation of nitroarene. Interestingly, the final catalytic product is strongly dependent on the nature of the hydrogen donor source. The yield of nitrobenzene reduction to aniline increased from 20% to an almost quantitative yield over a range of alcohols, diols and aminoalcohols. In glycerol at 130 degrees C aniline was isolated in 93% yield. In ethanolamine, the reaction was conveniently performed at a lower temperature (55 degrees C) and gave selectively substituted azobenzene (92% yield). Experimental studies provide support for a reaction pathway in which the Cu(0) NPs catalysed transfer hydrogenation of nitrobenzene to aniline proceeds via the condensation route. The high chemoselectivity of both protocols has been proved in experiments on a panel of variously substituted nitroarenes. Enabling technologies, microwaves and ultrasound, used both separately and in combination, have successfully increased the reaction rate and reaction yield.

Bye, fridends, I hope you can learn more about C8H7NO3, If you have any questions, you can browse other blog as well. See you lster.. Computed Properties of C8H7NO3

Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem

Category: benzodioxans. In 2019.0 ADV SYNTH CATAL published article about CARBONYL-COMPOUNDS; HYDROGEN-PEROXIDE; SELENIUM; EFFICIENT; OXIMES; ALKENES; FUNCTIONALIZATION; DEPROTECTION; ALDOXIMES; CLEAVAGE in [Chen, Chao; Zhang, Xu; Cao, Hongen; Wang, Fang; Yu, Lei; Xu, Qing] Yangzhou Univ, Sch Chem & Chem Engn, Guangling Coll, Yangzhou 225002, Jiangsu, Peoples R China; [Chen, Chao; Zhang, Xu; Cao, Hongen; Wang, Fang; Yu, Lei; Xu, Qing] Yangzhou Univ, Sch Hort & Plant Protect, Inst Pesticide, Yangzhou 225002, Jiangsu, Peoples R China; [Wang, Fang] Yangzhou Polytechnol Inst, Yangzhou 225127, Jiangsu, Peoples R China; [Xu, Qing] Wenzhou Univ, Coll Chem & Mat Engn, Wenzhou 325035, Zhejiang, Peoples R China in 2019.0, Cited 68.0. The Name is 1-(4-Nitrophenyl)ethanone. Through research, I have a further understanding and discovery of 100-19-6.

In contrast to conventional organoselenium-catalyzed oxidation reactions that require peroxide oxidants such as hydrogen peroxide, in this work we found that, addition of a low loading of iron (II) could enable the successful utilization of air as the terminal oxidant in organoselenium-catalyzed oxidative deoximation reaction of ketoximes. This led to a new mild and relatively green aerobic oxidative deoximation method. Control reactions and X-ray photoelectron spectroscopy (XPS) analysis suggest that iron is crucial in the catalytic cycle, working to prohibit the deactivation of selenium catalyst through an iron-catalyzed aerobic oxidation of low valent selenium species by air to the active high valent selenium species. Since air can be utilized as the terminal oxidant, this work may contribute to the advance of organoselenium catalysis.

About 1-(4-Nitrophenyl)ethanone, If you have any questions, you can contact Chen, C; Zhang, X; Cao, HG; Wang, F; Yu, L; Xu, Q or concate me.. Category: benzodioxans

Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem

An article High-Selectivity Fluorescent Reporter toward Peroxynitrite in a Coexisting Nonalcoholic Fatty Liver and Drug-Induced Liver Diseases Model WOS:000563047900068 published article about ENDOGENOUS PEROXYNITRITE; RATIOMETRIC DETECTION; NITRIC-OXIDE; LIVING CELLS; PROBE; HEPATOTOXICITY; VISUALIZATION; TOXICITY; STRESS; INJURY in [Cheng, Dan; Gong, Xiangyang; Wu, Qian; Yuan, Jie; Lv, Yun; Yuan, Lin; Zhang, Xiaobing] Hunan Univ, State Key Lab Chemo Biosensing & Chemometr, Coll Chem & Chem Engn, Changsha 410082, Peoples R China in 2020.0, Cited 49.0. Category: benzodioxans. The Name is 1-(4-Nitrophenyl)ethanone. Through research, I have a further understanding and discovery of 100-19-6

Peroxynitrite (ONOO-), a highly reactive species, is profoundly involved in many physiological and pathological processes. Change of the ONOO- level usually indicates an abnormal body function. Thus, it is desired to develop a highly reliable ONOO- assay to elucidate its roles in a related disease environment. In this work, we have constructed a ratiometric molecule fluorescent probe RTFP toward ONOO- with high specificity by the combination strategy of probe screening and a rational design method. RTFP displayed excellent detection sensitivity (detection limit: 4.1 nM) and produced a highly ratiometric emission signal (130-fold). Leveraging this probe, we showed the change of ONOO- content in the free-fatty-acid-induced nonalcoholic fatty liver disease (NAFLD) and acetaminophen-induced drug-induced liver injury (DILI) cellular model and for the first time disclosed the involved mechanism of cytochrome P450 2E1 (CYP2E1) enzyme in NAFLD with a DILI pathological environment. Furthermore, RTFP also was utilized to visualize ONOO- fluctuation of living liver tissues in a high-fat-diet-caused NAFLD model. We expected that this probe may help the study of liver injury in the exploration of mechanism and signal path.

Category: benzodioxans. Welcome to talk about 100-19-6, If you have any questions, you can contact Cheng, D; Gong, XY; Wu, Q; Yuan, J; Lv, Y; Yuan, L; Zhang, XB or send Email.

Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem

An article Na2S-promoted reduction of azides in water: synthesis of pyrazolopyridines in one pot and evaluation of antimicrobial activity WOS:000465614900012 published article about BIOLOGICAL EVALUATION; PRIMARY AMINES; EFFICIENT; DERIVATIVES; REAGENT; INHIBITORS; CONVERSION; DISCOVERY; DESIGN; ACID in [Kale, Ashok; Medishetti, Nagaraju; Atmakur, Krishnaiah] Indian Inst Chem Technol, CSIR, Fluoro & Agro Chem Dept, Hyderabad 500007, Telangana, India; [Kanugala, Sirisha; Kumar, Ganesh C.] Indian Inst Chem Technol, CSIR, Med Chem & Pharmacol Div, Hyderabad 500007, Telangana, India; [Kale, Ashok; Medishetti, Nagaraju; Kanugala, Sirisha; Atmakur, Krishnaiah] Indian Inst Chem Technol, AcSIR, Hyderabad 500007, Telangana, India in 2019.0, Cited 48.0. Recommanded Product: 1-(4-Nitrophenyl)ethanone. The Name is 1-(4-Nitrophenyl)ethanone. Through research, I have a further understanding and discovery of 100-19-6

Reduction of various azides using Na2S has been accomplished in water, and, in situ, the resulting amines on reaction with various ketones lead to pyrazolo[3,4-b]pyridines in one pot. Thus, a number of new trifluoromethyl-substituted pyrazolo[3,4-b]pyridine compounds have been prepared and screened for antimicrobial activity against different Gram-positive and Gram-negative strains. A good number of compounds, 4a, 4b, 4d, 4f, 4i, 4k, 4l, 4m, 4r and 4s, were found to possess promising activity. Notably, Na2S on hydrolysis in water generates H2S and NaOH, which facilitate the reduction of azides followed by intramolecular cyclization leading to the title compounds. To the best of our knowledge, this is the first report of the synthesis of the title compounds in aqueous medium in a one-pot reaction.

Recommanded Product: 1-(4-Nitrophenyl)ethanone. About 1-(4-Nitrophenyl)ethanone, If you have any questions, you can contact Kale, A; Medishetti, N; Kanugala, S; Kumar, CG; Atmakur, K or concate me.

Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem

An article Synthesis and Structure-Activity Relationship of Dual-Stage Antimalarial Pyrazolo[3,4-b]pyridines WOS:000585952100032 published article about MOLECULAR-DYNAMICS SIMULATIONS; DRUG DISCOVERY; RESISTANCE; ACCURACY; AMBER; GAMETOCYTES; DESIGN in [Hammill, Jared T.; Rice, Amy L.; Falade, Mofolusho O.; Guy, R. Kiplin] Univ Kentucky, Dept Pharmaceut Sci, Lexington, KY 40508 USA; [Sigal, Martina] St Jude Childrens Res Hosp, Dept Chem Biol & Therapeut, 332 N Lauderdale St, Memphis, TN 38105 USA; [Eagon, Scott; Ahn, Kevin J.; Tryhorn, Julia E.; Belanger, Briana; Chaplan, Cory A.; Loop, Lauren; Kashtanova, Anna S.; Wilkinson, Steven P.; Takahashi, Rei; Kim, Katie; Cheung, Ashley; DiBernardo, Celine] Calif Polytech State Univ San Luis Obispo, Dept Chem & Biochem, San Luis Obispo, CA 93407 USA; [Koch, Grant] Univ Calif Santa Cruz, Dept Chem & Biochem, Santa Cruz, CA 95064 USA; [Yniguez, Kenya] SRI Int, Menlo Pk, CA 94025 USA; [Lazaro, Horacio; Kimball, Joshua J.] Promega Biosci, San Luis Obispo, CA 93401 USA; [Winzeler, Elizabeth A.; Eribez, Korina; Mittal, Nimisha] Univ Calif San Diego, Sch Med, La Jolla, CA 92093 USA; [Gamo, Francisco-Javier; Crespo, Benigno] GlaxoSmithKline, DDW, Global Hlth, Madrid 28760, Spain; [Churchyard, Alisje; Garcia-Barbazan, Irene; Baum, Jake] Imperial Coll London, Dept Life Sci, London SW7 2AZ, England; [Anderson, Marc O.] San Francisco State Univ, Dept Chem & Biochem, San Francisco, CA 94132 USA; [Laleu, Benoit] Med Malaria Venture MMV, CH-1215 Geneva, Switzerland in 2020.0, Cited 56.0. COA of Formula: C8H7NO3. The Name is 1-(4-Nitrophenyl)ethanone. Through research, I have a further understanding and discovery of 100-19-6

Malaria remains one of the most deadly infectious diseases, causing hundreds of thousands of deaths each year, primarily in young children and pregnant mothers. Here, we report the discovery and derivatization of a series of pyrazolo[3,4-b]pyridines targeting Plasmodium falciparum, the deadliest species of the malaria parasite. Hit compounds in this series display sub-micromolar in vitro activity against the intraerythrocytic stage of the parasite as well as little to no toxicity against the human fibroblast BJ and liver HepG2 cell lines. In addition, our hit compounds show good activity against the liver stage of the parasite but little activity against the gametocyte stage. Parasitological profiles, including rate of killing, docking, and molecular dynamics studies, suggest that our compounds may target the Q(o) binding site of cytochrome bc(1).

Welcome to talk about 100-19-6, If you have any questions, you can contact Eagon, S; Hammill, JT; Sigal, M; Ahn, KJ; Tryhorn, JE; Koch, G; Belanger, B; Chaplan, CA; Loop, L; Kashtanova, AS; Yniguez, K; Lazaro, H; Wilkinson, SP; Rice, AL; Falade, MO; Takahashi, R; Kim, K; Cheung, A; DiBernardo, C; Kimball, JJ; Winzeler, EA; Eribez, K; Mittal, N; Gamo, FJ; Crespo, B; Churchyard, A; Garcia-Barbazan, I; Baum, J; Anderson, MO; Laleu, B; Guy, RK or send Email.. COA of Formula: C8H7NO3

Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem

An article Visible-Light-DrivenZ-Selective Reaction of Methyl Ketones with DMSO: A Mild Synthetic Approach to Methylthio-Substituted 1,4-Enedione Promoted by Selectfluor (TM) WOS:000578661700001 published article about C-H-FUNCTIONALIZATION; METAL-FREE; PHOTOREDOX CATALYSIS; OXIDATIVE AMINATION; DIMETHYL-SULFOXIDE; STEREOSELECTIVE-SYNTHESIS; MICHAEL ADDITION; ROOM-TEMPERATURE; FACILE SYNTHESIS; BOND FORMATION in [Rastogi, Gaurav K.; Deb, Mohit L.; Baruah, Pranjal K.] Gauhati Univ, Dept Appl Sci, GUIST, Gauhati 781014, Assam, India; [Rastogi, Gaurav K.] CSIR NEIST, A Dept Appl Organ Chem, Jorhat 785006, Assam, India in 2021.0, Cited 111.0. The Name is 1-(4-Nitrophenyl)ethanone. Through research, I have a further understanding and discovery of 100-19-6. Name: 1-(4-Nitrophenyl)ethanone

Here we disclose a simple, visible-light-drivenZ-selective synthesis of methylthio-substituted 1,4-enedione in a single step promoted by Selectfluor. Dimethyl sulfoxide is used as both the ‘thio’ source and the solvent. Molecular iodine and potassium persulfate are used as catalyst and oxidant, respectively. White light (CFL-30W) is used as the light source. The proposed mechanism involves a Kornblum reaction followed by aldol reaction.

Name: 1-(4-Nitrophenyl)ethanone. Bye, fridends, I hope you can learn more about C8H7NO3, If you have any questions, you can browse other blog as well. See you lster.

Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem

In 2021.0 ACS APPL MATER INTER published article about IONIC LIQUID; EFFICIENT; CO2; CYCLOADDITION; CATALYST in [Du, Yi-Ran; Xu, Bao-Hua; Xia, Shi-Ping; Ding, Guang-Rong; Zhang, Suo-Jiang] Chinese Acad Sci, Innovat Acad Green Manufacture, Inst Proc Engn, Beijing Key Lab Ion Liquids Clean Proc, Beijing 100190, Peoples R China; [Du, Yi-Ran; Xu, Bao-Hua; Ding, Guang-Rong; Zhang, Suo-Jiang] Univ Chinese Acad Sci, Sch Chem & Chem Engn, Beijing 100049, Peoples R China; [Xia, Shi-Ping] East China Univ Sci & Technol, State Key Lab Chem Engn, Shanghai 200237, Peoples R China in 2021.0, Cited 49.0. The Name is 1-(4-Nitrophenyl)ethanone. Through research, I have a further understanding and discovery of 100-19-6. Recommanded Product: 100-19-6

In this study, the covalent bonding of linear poly(ionic liquids (PILs) with covalent organic frameworks (COFs) was accessed by copolymerization of a vinyl-decorated COF with 4-vinylbenzyl chloride, followed by quaternization with tertiary amines. The resultant PIL-COF composite by anchoring a proper content of vinyl sites on the COF-based comonomer retains the crystallinity and porosity, thereby facilitating access of the reactants to the catalytic active sites. As a proof of concept, the dehydrative transformation of sorbitol into isosorbide was selected as a benchmark reaction, whose rate improved significantly in the presence of PIL-COF-0.33 compared with those of individual components and the mesoporous PIL counterpart due to uniform pore sizes and flexible linear catalytic chains. In addition, the hybrids bearing a chemical cross-linkage between PILs and COFs are robust, and PIL-COF-0.33 can be recovered and reused for 10 runs without significant reactivity loss. These findings provide the basis for a novel design concept for achieving both efficient and stable IL catalysis.

Welcome to talk about 100-19-6, If you have any questions, you can contact Du, YR; Xu, BH; Xia, SP; Ding, GR; Zhang, SJ or send Email.. Recommanded Product: 100-19-6

Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem