Day: November 8, 2021

An article A general asymmetric copper-catalysed Sonogashira C(sp(3))-C(sp) coupling WOS:000498875700019 published article about CROSS-COUPLINGS; ALKYL BROMIDES; ACETYLENE; NICKEL; ARYL; METHODOLOGY; DERIVATIVES; ALDEHYDES; HYDROGEN; IODIDES in [Dong, Xiao-Yang; Zhang, Yu-Feng; Ma, Can-Liang; Wang, Fu-Li; Jiang, Sheng-Peng; Liu, Xin-Yuan] Southern Univ Sci & Technol, Shenzhen Grubbs Inst, Shenzhen, Guangdong, Peoples R China; [Dong, Xiao-Yang; Zhang, Yu-Feng; Ma, Can-Liang; Gu, Qiang-Shuai; Wang, Fu-Li; Li, Zhong-Liang; Jiang, Sheng-Peng; Liu, Xin-Yuan] Southern Univ Sci & Technol, Dept Chem, Shenzhen, Guangdong, Peoples R China; [Gu, Qiang-Shuai; Li, Zhong-Liang] Southern Univ Sci & Technol, Acad Adv Interdisciplinary Studies, Shenzhen, Guangdong, Peoples R China in 2019, Cited 54. The Name is 2,2-Diphenylacetonitrile. Through research, I have a further understanding and discovery of 86-29-3. Formula: C14H11N

Continued development of the Sonogashira coupling has made it a well established and versatile reaction for the straightforward formation of C-C bonds, forging the carbon skeletons of broadly useful functionalized molecules. However, asymmetric Sonogashira coupling, particularly for C(sp(3))-C(sp) bond formation, has remained largely unexplored. Here we demonstrate a general stereoconvergent Sonogashira C(sp(3))-C(sp) cross-coupling of a broad range of terminal alkynes and racemic alkyl halides (>120 examples) that are enabled by copper-catalysed radical-involved alkynylation using a chiral cinchona alkaloid-based P,N-ligand. Industrially relevant acetylene and propyne are successfully incorporated, laying the foundation for scalable and economic synthetic applications. The potential utility of this method is demonstrated in the facile synthesis of stereoenriched bioactive or functional molecule derivatives, medicinal compounds and natural products that feature a range of chiral C(sp(3))-C(sp/sp(2)/sp(3)) bonds. This work emphasizes the importance of radical species for developing enantioconvergent transformations.

Formula: C14H11N. About 2,2-Diphenylacetonitrile, If you have any questions, you can contact Dong, XY; Zhang, YF; Ma, CL; Gu, QS; Wang, FL; Li, ZL; Jiang, SP; Liu, XY or concate me.

Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem

In 2021 RSC ADV published article about ONE-POT SYNTHESIS; ARYL HALIDES; ARYLATION; CHEMISTRY; COMPLEX; PERSPECTIVE; AMIDATION; EFFICIENT; REAGENTS; SYSTEM in [Sallio, Romain; Pakulski, Pawel; Diachenko, Iryna; Berteina-Raboin, Sabine; Colas, Cyril; Gillaizeau, Isabelle] Univ Orleans, Inst Organ & Analyt Chem, ICOA UMR 7311 CNRS, Rue Chartres, F-45100 Orleans, France; [Payard, Pierre-Adrien; Fabre, Indira; Grimaud, Laurence] PSL Univ, Sorbonne Univ, Dept Chim,CNRS, Lab Biomol,LBM,Ecole Normale Super, F-75005 Paris, France; [Ciofini, Ilaria] PSL Univ, Inst Chem Hlth & Life Sci, CNRS, Chim ParisTech,I CLeHS, F-75005 Paris, France in 2021, Cited 38. The Name is 2,2-Diphenylacetonitrile. Through research, I have a further understanding and discovery of 86-29-3. Name: 2,2-Diphenylacetonitrile

This work reports a simple and efficient method for the copper-catalyzed redox-neutral transformation of alkyl nitriles using eco-friendly diaryliodonium salts and leading to N-arylacetamides. The method features high efficiency, broad substrate scope and good functional group tolerance.

About 2,2-Diphenylacetonitrile, If you have any questions, you can contact Sallio, R; Payard, PA; Pakulski, P; Diachenko, I; Fabre, I; Berteina-Raboin, S; Colas, C; Ciofini, I; Grimaud, L; Gillaizeau, I or concate me.. Name: 2,2-Diphenylacetonitrile

Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem

An article Synthesis and Anticancer Activity of N-(di/trimethoxyaryl)-5-arylisoxazole-3-carboxamide WOS:000583587600026 published article about BIOLOGICAL EVALUATION; CYTOTOXIC ACTIVITY; IN-VITRO; ISOXAZOLE; INHIBITION; APOPTOSIS; CURCUMIN; GROWTH in [Saeedi, Mina] Univ Tehran Med Sci, Fac Pharm, Med Plants Res Ctr, Tehran, Iran; [Saeedi, Mina; Karimpour-Razkenari, Elahe; Akbarzadeh, Tahmineh] Univ Tehran Med Sci, Persian Med & Pharm Res Ctr, Tehran, Iran; [Hashemi, Mehdi; Rafinejad, Ali; Akbarzadeh, Tahmineh] Univ Tehran Med Sci, Fac Pharm, Dept Med Chem, Tehran, Iran; [Mahdavi, Mohammad] Univ Tehran Med Sci, Endocrinol & Metab Clin Sci Inst, Endocrinol & Metab Res Ctr, Tehran, Iran; [Najafi, Zahra] Hamadan Univ Med Sci, Sch Pharm, Dept Med Chem, Hamadan, Hamadan, Iran; [Mirfazli, Seyedeh Sara] Iran Univ Med Sci, Sch Pharm, Dept Med Chem, Int Campus, Tehran, Iran; [Mohammadian, Razieh; Kabudanian Ardestani, Sussan] Univ Tehran, Inst Biochem & Biophys, Dept Biochem, Tehran, Iran; [Safavi, Maliheh] Iranian Res Org Sci & Technol, Dept Biotechnol, Tehran, Iran in 2020.0, Cited 30.0. Product Details of 100-19-6. The Name is 1-(4-Nitrophenyl)ethanone. Through research, I have a further understanding and discovery of 100-19-6

In this study, a new series of N-(di or trimethoxyaryl)-5-arylisoxazole-3-carboxamide derivatives were synthesized and evaluated against human breast cancer cell lines including MCF-7, MDA-MB-231, and T-47D. Among the synthesized compounds, 5-(m-tolyl)-N-(3,4,5-trimethoxyphenyl)isoxazole-3-carboxamide (8f) showed significant cytotoxicity against all three cell lines comparing with etoposide as the reference drug. Also, Annexin V-FITC/propidium iodide and acridine orange/ethidium bromide staining assay were performed to validate apoptotic activity of compound 8f. The results confirmed induction of apoptosis at early stage.

Product Details of 100-19-6. Welcome to talk about 100-19-6, If you have any questions, you can contact Saeedi, M; Hashemi, M; Mahdavi, M; Rafinejad, A; Najafi, Z; Mirfazli, SS; Mohammadian, R; Karimpour-Razkenari, E; Ardestani, SK; Safavi, M; Akbarzadeh, T or send Email.

Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem

Recently I am researching about NIGELLA-SATIVA L.; PRUNUS-SPINOSA L.; CLOVE SYZYGIUM-AROMATICUM; BARBERRY FRUIT EXTRACT; ROSA-CANINA L.; MORUS-NIGRA L.; CHEMICAL-COMPOSITION; FACILE SYNTHESIS; ANTIMICROBIAL ACTIVITY; EFFICIENT REDUCTION, Saw an article supported by the . Published in PERGAMON-ELSEVIER SCIENCE LTD in OXFORD ,Authors: Kurt, BZ; Durmus, Z; Sevgi, E. The CAS is 100-19-6. Through research, I have a further understanding and discovery of 1-(4-Nitrophenyl)ethanone. Safety of 1-(4-Nitrophenyl)ethanone

The reduction of graphene oxide (GO) was examined by using the extracts of different plants; cloves, white mulberry, black cumin seed, blackthorn, dark grape, and rosehip. The reduction efficiency of extracts was confirmed by XRD and spectroscopic analysis. The layered structure of reduced graphene and graphene nanocomposite decorated with palladium nanoparticles (PdNPs) was observed by electron microscopy techniques. This nanocomposite considered to be an active-selective catalyst for hydrogenation of nitroarenes in organic synthesis. This efficient catalyst can provide to develop clean, environmentally friendly, and energy-efficient production routes in industrial organic chemistry. It was concluded that the PdNPs/RGO catalyst showed high stability based on its reusing performance; seven times without loss of catalytic activity. (C) 2019 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.

Safety of 1-(4-Nitrophenyl)ethanone. About 1-(4-Nitrophenyl)ethanone, If you have any questions, you can contact Kurt, BZ; Durmus, Z; Sevgi, E or concate me.

Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem

SDS of cas: 100-19-6. In 2020.0 CHEM PAP published article about SODIUM-BOROHYDRIDE REDUCTIONS; PHYSICOCHEMICAL PROPERTIES; THERMOPHYSICAL PROPERTIES; AMINO-ACIDS; DESIGN; RECOGNITION; SEPARATION; ADDITIVES; SOLVENTS; ORGANOCATALYSTS in [Gondal, Humaira Yasmeen; Mumtaz, Salma; Mumtaz, Nargis] Univ Sargodha, Dept Chem, Sargodha 40100, Pakistan; [Mumtaz, Salma; Cano, Israel] Univ Nottingham, GSK Carbon Neutral Lab Sustainable Chem, Nottingham NG7 2GA, England; [Abbaskhan, Ahmed] Univ Karachi, ICCBS, HEJ Res Inst Chem, Karachi 75270, Pakistan; [Cano, Israel] Univ Cantabria, Fac Ciencias, Dept Fis Aplicada, E-39005 Santander, Spain in 2020.0, Cited 83.0. The Name is 1-(4-Nitrophenyl)ethanone. Through research, I have a further understanding and discovery of 100-19-6.

An efficient solvent-free synthesis of a new family of functionalized chiral ionic liquids based on pyridinium cation has been developed from low-cost chiral terpenoid alcohols. An exhaustive characterization was performed using state-of-the-art techniques, such as ESI-MS, ATR FT-IR and NMR (H-1, C-13, B-11, P-31, F-19) spectroscopy. Thermal properties of this new class of chiral ionic liquids were studied by TGA and DSC analyses. Catalytic potential of the synthesized CILS was also evaluated in the asymmetric reduction of prochiral acetophenones.

SDS of cas: 100-19-6. Bye, fridends, I hope you can learn more about C8H7NO3, If you have any questions, you can browse other blog as well. See you lster.

Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem

Recommanded Product: 1-(4-Nitrophenyl)ethanone. In 2019.0 EUR J ORG CHEM published article about ESTERS; HYDROBORATION; BORYLATION; ALKYNES; DIVERSIFICATION; CARBANIONS in [Kovalenko, Maksym; Yarmoliuk, Dmytro, V; Serhiichuk, Dmytro; Chernenko, Dania; Smyrnov, Vladyslav; Breslayskyi, Artur; Hryshchuk, Oleksandr, V; Kleban, Ihor; Tymtsunik, Andriy, V; Tolmachev, Andrey A.; Kuchkovska, Yuliya O.; Grygorenko, Oleksandr O.] Enamine Ltd, Chervonotkatska St 78, UA-02094 Kiev, Ukraine; [Yarmoliuk, Dmytro, V; Smyrnov, Vladyslav; Hryshchuk, Oleksandr, V; Tolmachev, Andrey A.; Kuchkovska, Yuliya O.; Grygorenko, Oleksandr O.] Tams Shevchenko Natl Univ Kyiv, Volodymyrska St 60, UA-01601 Kiev, Ukraine; [Kleban, Ihor; Rassukana, Yuliya] Natl Acad Sci Ukraine, Inst Organ Chem, Murmanska St 5, UA-02660 Kiev, Ukraine; [Chernenko, Dania; Rassukana, Yuliya; Tymtsunik, Andriy, V] Natl Tech Univ Ukraine, Igor Sikorsky Kyiv Polytech Inst, Prospect Perem 37, UA-03056 Kiev, Ukraine in 2019.0, Cited 50.0. The Name is 1-(4-Nitrophenyl)ethanone. Through research, I have a further understanding and discovery of 100-19-6.

Preparation of 2,2-disubstituted and 2-monosubstituted alkenylboronic acid esters from aliphatic and aromatic ketones and aldehydes by the boron-Wittig olefination with bis[(pinacolato)boryl]methane was examined and applied on the multigram scale. The influence of the substrate steric and electronic features on the overall efficiency and stereochemical outcome of the reaction was studied. Additionally, a series of diversely functionalized (hetera)cycloalkylidenemethyl and (hetera)cycloalkyl boronic acid-derived building blocks was synthesized.

Recommanded Product: 1-(4-Nitrophenyl)ethanone. Bye, fridends, I hope you can learn more about C8H7NO3, If you have any questions, you can browse other blog as well. See you lster.

Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem

Authors Ashraf, MA; Liu, ZL; Li, C; Zhang, DQ in WILEY published article about CATALYZED SYNTHESIS; 3-COMPONENT SYNTHESIS; EFFICIENT SYNTHESIS; ACID CATALYST; TETRAZOLES; NITRILES; NANOPARTICLES; 5-SUBSTITUTED-1H-TETRAZOLES; DERIVATIVES; CONVERSION in [Ashraf, Muhammad Aqeel; Li, Cheng; Zhang, Dangquan] Henan Agr Univ, Sch Forestry, Zhengzhou 450002, Peoples R China; [Ashraf, Muhammad Aqeel] China Univ Geosci, Sch Environm Studies, Wuhan 430074, Peoples R China; [Liu, Zhenling] Henan Univ Technol, Sch Management, Zhengzhou 450001, Peoples R China in 2021, Cited 46. Category: benzodioxans. The Name is 2,2-Diphenylacetonitrile. Through research, I have a further understanding and discovery of 86-29-3

An efficient and sustainable synthetic protocol has been presented to synthesis and 5-substituted 1H-tetrazole privileged heterocyclic substructures. The synthetic protocol involves two-component reaction between aryl nitriles and NaN3 in water using complex of L-lysine-palladium nanoparticles (NPs) modified Fe3O4 nanoparticles as magnetically separable, recyclable, and reusable heterogeneous catalyst. Magnetically retrievable L-lysine-Pd(0) modified Fe3O4 nanoparticles were applied in [2 + 3] cycloaddition synthesis of 5-substituted 1H-tetrazoles. The advantages of this strategy include easy recovery and efficient reusability of the expensive Pd NPs, obtaining high yields of [2 + 3] cycloaddition, short reaction times, and all of the reported synthetic strategies are being performed in water as green solvent for a wide range of substrates.

Category: benzodioxans. Bye, fridends, I hope you can learn more about C14H11N, If you have any questions, you can browse other blog as well. See you lster.

Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem

Recently I am researching about N-ARYLSULFONAMIDE FORMATION; SELECTIVE HYDROGENATION; ARYL SULFONAMIDES; METAL-CATALYSTS; AMINE FORMATION; ALKYLATION; ALCOHOLS; CHLORIDES; CONDENSATION; AMIDATION, Saw an article supported by the Normal Project Foundation of Hunan Provincial Education Department [18C0845]; Key Project Foundation of Hunan Provincial Education Department [18A396]. Published in MDPI in BASEL ,Authors: Liu, SW; Chen, R; Zhang, J. The CAS is 100-19-6. Through research, I have a further understanding and discovery of 1-(4-Nitrophenyl)ethanone. SDS of cas: 100-19-6

A simple copper-catalyzed redox coupling of sodium sulfinates and nitroarenes is described. In this process, abundant and stable nitroarenes serve as both the nitrogen sources and oxidants, and sodium sulfinates act as both reactants and reductants. A variety of aromatic sulfonamides were obtained in moderate to good yields with broad substrate scope. No external additive is employed for this kind of transformation.

Welcome to talk about 100-19-6, If you have any questions, you can contact Liu, SW; Chen, R; Zhang, J or send Email.. SDS of cas: 100-19-6

Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem

Safety of 1-(4-Nitrophenyl)ethanone. In 2020.0 DALTON T published article about ENERGY-ADJUSTED PSEUDOPOTENTIALS; MOLECULAR-ORBITAL METHODS; TRANSITION-METAL OXOS; CARBONYL-COMPOUNDS; BASIS-SETS; B(C6F5)(3)-CATALYZED HYDROSILYLATION; MECHANISM; KETONES; ELECTRON; APPROXIMATION in [Brown, Caleb A.; Abrahamse, Michael; Ison, Elon A.] North Carolina State Univ, Dept Chem, 2620 Yarbrough Dr, Raleigh, NC 27695 USA in 2020.0, Cited 54.0. The Name is 1-(4-Nitrophenyl)ethanone. Through research, I have a further understanding and discovery of 100-19-6.

A pathway for the catalytic hydrosilylation of carbonyl substrates with M(C6F5)(3) (M = B, Al and Ga) was calculated by DFT (B3PW91-D3) and it was shown that in the case of the Al reagent, the carbonyl substrate binds irreversibly and inhibits catalysis by generating a stable carbonyl adduct. In contrast, the reduced electrophilicity of B(C6F5)(3) disfavors the binding of the carbonyl substrate and increases the concentration of an activated silane adduct which is the species responsible for catalytic turnover. A similar mechanism was found for both cationic and neutral Re(III) species. Further, it was shown by tuning the electrophilicity of the rhenium catalysts, conditions can be found that would enable the catalytic hydrosilylation of ketone and nitrile substrates that were unreactive in previously reported systems. Thus the mechanisms proposed in this work, lay the foundation for the design of new catalytic systems.

Welcome to talk about 100-19-6, If you have any questions, you can contact Brown, CA; Abrahamse, M; Ison, EA or send Email.. Safety of 1-(4-Nitrophenyl)ethanone

Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem

An article Efficient Transfer Hydrogenation of Ketones using Methanol as Liquid Organic Hydrogen Carrier WOS:000533699900001 published article about DEHYDROGENATIVE OXIDATION; TO-HYDROCARBONS; BIPYRIDONATE LIGAND; CATALYTIC-SYSTEM; ALCOHOLS; COMPLEX; PHASE; CONVERSION; REDUCTION; BEARING in [Garg, Nidhi; Paira, Soumen; Sundararaju, Basker] Indian Inst Technol Kanpur, Dept Chem, Kanpur 208016, Uttar Pradesh, India in 2020.0, Cited 48.0. Safety of 1-(4-Nitrophenyl)ethanone. The Name is 1-(4-Nitrophenyl)ethanone. Through research, I have a further understanding and discovery of 100-19-6

Herein, we demonstrate an efficient protocol for transfer hydrogenation of ketones using methanol as practical and useful liquid organic hydrogen carrier (LOHC) under Ir(III) catalysis. Various ketones, including electron-rich/electron-poor aromatic ketones, heteroaromatic and aliphatic ketones, have been efficiently reduced into their corresponding alcohols. Chemoselective reduction of ketones was established in the presence of various other reducible functional groups under mild conditions.

Welcome to talk about 100-19-6, If you have any questions, you can contact Garg, N; Paira, S; Sundararaju, B or send Email.. Safety of 1-(4-Nitrophenyl)ethanone

Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem