Month: October 2021

Recommanded Product: 100-19-6. Authors Rai, P; Chettri, P; Kar, S; Nagar, MA; Srivastava, S; Golakoti, NR in SPRINGER INTERNATIONAL PUBLISHING AG published article about in [Rai, Prashant; Kar, Swayamsiddha; Golakoti, Nageswara Rao] Sri Sathya Sai Inst Higher Learning, Dept Chem, Prasanthinilayam 515134, Andhra Pradesh, India; [Chettri, Prajal; Nagar, Malhar Anupam; Srivastava, Shailesh] Sri Sathya Sai Inst Higher Learning, Dept Phys, Prasanthinilayam 515134, Andhra Pradesh, India in 2021, Cited 35. The Name is 1-(4-Nitrophenyl)ethanone. Through research, I have a further understanding and discovery of 100-19-6

Fifteen chalcone derivatives having D-A-D, D-A-A and A-A-D architectures have been synthesized by Claisen-Schmidt condensation reaction and characterized by UV-Vis, IR, H-1-NMR, C-13-NMR and Mass spectrometry. In order to unambiguously establish the structure-activity relationship for the non-linear optical activity of these compounds, for the first time to our knowledge, we use the femtosecond degenerate four wave mixing (DFWM) technique to quantify and compare the third-order non-linear optical (NLO) activity of all the 15 compounds, under identical conditions. The second harmonics generation (SHG) efficiencies for all the compounds have also been evaluated using the Kurtz-Perry powder method. Among the compounds that we have synthesized here, the ones with A-A-D architecture show the highest NLO activity. Our results show that the NLO activity of a compound with A-A-D architecture can be further enhanced by incorporating a substituent with strong electron withdrawing ability on ring A and strong electron donating substituent on ring B. The results of the in silico studies that we have carried out correlate well with our experimental findings. The compounds (E)-3-(4-(dimethylamino)phenyl)-1-(4-nitrophenyl)prop-2-en-1-one with the compound code (4-N(CH3)(2)-4 ‘-NO2) and (E)-3-(4-methoxyphenyl)-1-(4-nitrophenyl)prop-2-en-1-one with the compound code (4-MeO-4 ‘-NO2) show the highest NLO activity among the compounds we have reported here.

Recommanded Product: 100-19-6. About 1-(4-Nitrophenyl)ethanone, If you have any questions, you can contact Rai, P; Chettri, P; Kar, S; Nagar, MA; Srivastava, S; Golakoti, NR or concate me.

Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem

Recently I am researching about MONOAMINE-OXIDASE-B; HIGH-POTENCY; IN-VITRO; MAO; SCAFFOLD; DESIGN; AGENTS; IDENTIFICATION, Saw an article supported by the Progetto di Ricerca Ateneo La Sapienza (Italy) [C26A14AC5L]; POR FESR LAZIO 2014/2020 – REGIONE LAZIO – Avviso pubblico LIFE 2020. Published in TAYLOR & FRANCIS LTD in ABINGDON ,Authors: Secci, D; Carradori, S; Petzer, A; Guglielmi, P; D’Ascenzio, M; Chimenti, P; Bagetta, D; Alcaro, S; Zengin, G; Petzer, JP; Ortuso, F. The CAS is 100-19-6. Through research, I have a further understanding and discovery of 1-(4-Nitrophenyl)ethanone. SDS of cas: 100-19-6

A new series of 4-(3-nitrophenyl)thiazol-2-ylhydrazone derivatives were designed, synthesised, and evaluated to assess their inhibitory effect on the human monoamine oxidase (hMAO) A and B isoforms. Different (un)substituted (hetero)aromatic substituents were linked to N1 of the hydrazone in order to establish robust structure-activity relationships. The results of the biological testing demonstrated that the presence of the hydrazothiazole nucleus bearing at C4 a phenyl ring functionalised at the meta position with a nitro group represents an important pharmacophoric feature to obtain selective and reversible human MAO-B inhibition for the treatment of neurodegenerative disorders. In addition, the most potent and selective MAO-B inhibitors were evaluated in silico as potential cholinesterase (AChE/BuChE) inhibitors and in vitro for antioxidant activities. The results obtained from molecular modelling studies provided insight into the multiple interactions and structural requirements for the reported MAO inhibitory properties.

About 1-(4-Nitrophenyl)ethanone, If you have any questions, you can contact Secci, D; Carradori, S; Petzer, A; Guglielmi, P; D’Ascenzio, M; Chimenti, P; Bagetta, D; Alcaro, S; Zengin, G; Petzer, JP; Ortuso, F or concate me.. SDS of cas: 100-19-6

Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem

Name: 1-(4-Nitrophenyl)ethanone. I found the field of Chemistry; Science & Technology – Other Topics very interesting. Saw the article Zn(0)-Catalysed mild and selective hydrogenation of nitroarenes published in 2020.0, Reprint Addresses Wang, B (corresponding author), Hainan Univ, Minist Educ, Key Lab Adv Mat Trop Isl Resources, 58 Renmin AVE, Haikou 570228, Hainan, Peoples R China.; Wang, B (corresponding author), Shandong Agr Univ, Coll Sci & Engn, 7 Panhe AVE, Tai An 271017, Shandong, Peoples R China.. The CAS is 100-19-6. Through research, I have a further understanding and discovery of 1-(4-Nitrophenyl)ethanone.

The hydrogenation of nitroarenes is one of the most important strategies for the preparation of anilines. However, it is still a great challenge to develop mild and efficient synthetic routes toward aniline synthesis, particularly those employing both non-precious metal catalysts and low-pressure H-2. Herein, we report a highly efficient protocol for the selective hydrogenation of nitroarenes in neutral H2O using H-2(1 atm) over a heterogeneous Zn(0) catalyst under mild conditions. The nitro groups of an array of nitroarenes can be converted into -NH(2)with up to 99% conversions and a selectivity of >99%, even when functionalized with easily reducible substituents, or in the presence of aromatic ketones or styrene. This study might open an avenue for the selective hydrogenation of nitroarenes over a zinc catalyst using 1 atm H-2.

About 1-(4-Nitrophenyl)ethanone, If you have any questions, you can contact Sun, ST; Du, MY; Zhao, RX; Jv, XC; Hu, P; Zhang, Q; Wang, B or concate me.. Name: 1-(4-Nitrophenyl)ethanone

Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem

Li, PG; Zhu, H; Fan, M; Yan, C; Shi, K; Chi, XW; Zou, LH in [Li, Ping-Gui; Zhu, Hao; Fan, Min; Yan, Cheng; Shi, Kai; Chi, Xi-Wen; Zou, Liang-Hua] Jiangnan Univ, Minist Educ, Sch Pharmaceut Sci, Key Lab Carbohydrate Chem & Biotechnol, Lihu Ave 1800, Wuxi 214122, Jiangsu, Peoples R China; [Li, Ping-Gui] Nanjing Univ, Sch Chem & Chem Engn, State Key Lab Coordinat Chem, Xianlin Ave 163, Nanjing 210093, Jiangsu, Peoples R China published Copper-catalyzed coupling of anthranils and alpha-keto acids: direct synthesis of alpha-ketoamides in 2019.0, Cited 76.0. Category: benzodioxans. The Name is 1-(4-Nitrophenyl)ethanone. Through research, I have a further understanding and discovery of 100-19-6.

Copper-catalyzed coupling of alpha-keto acids with anthranils is reported for the synthesis of alpha-ketoamides. This process involves N-O/C-O bond cleavages and C-N bond formation. Furthermore, the decarboxylation of alpha-keto acids can be successfully suppressed under redox-neutral conditions.

Category: benzodioxans. About 1-(4-Nitrophenyl)ethanone, If you have any questions, you can contact Li, PG; Zhu, H; Fan, M; Yan, C; Shi, K; Chi, XW; Zou, LH or concate me.

Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem

Authors Ioannou, DI; Gioftsidou, DK; Tsina, VE; Kallitsakis, MG; Hatzidimitriou, AG; Terzidis, MA; Angaridis, PA; Lykakis, IN in AMER CHEMICAL SOC published article about in [Ioannou, Dimitris I.; Gioftsidou, Dimitra K.; Tsina, Vasiliki E.; Kallitsakis, Michael G.; Hatzidimitriou, Antonios G.; Angaridis, Panagiotis A.; Lykakis, Ioannis N.] Aristotle Univ Thessaloniki, Dept Chem, Thessaloniki 54124, Greece; [Terzidis, Michael A.] Int Hellen Univ, Dept Nutr Sci & Dietet, Thessaloniki 57400, Greece in 2021, Cited 48. COA of Formula: C8H7NO3. The Name is 1-(4-Nitrophenyl)ethanone. Through research, I have a further understanding and discovery of 100-19-6

We report an efficient catalytic protocol that chemo-selectively reduces nitroarenes to arylamines, by using methylhydrazine as a reducing agent in combination with the easily synthesized and robust catalyst tris(N-heterocyclic thioamidate) Co(III) complex [Co(kappa S,N-tfmp2S)(3)], tfmp2S = 4-(trifluoromethyl)-pyrimidine-2-thiolate. A series of arylamines and heterocyclic amines were formed in excellent yields and chemoselectivity. High conversion yields of nitroarenes into the corresponding amines were observed by using polar protic solvents, such as MeOH and ‘PrOH. Among several hydrogen donors that were examined, methylhydrazine demonstrated the best performance. Preliminary mechanistic investigations, supported by UV-vis and NMR spectroscopy, cyclic voltammetry, and high-resolution mass spectrometry, suggest a cooperative action of methylhydrazine and [Co(kappa S,N-tfmp2S)(3)] via a coordination activation pathway that leads to the formation of a reduced cobalt species, responsible for the catalytic transformation. In general, the corresponding N-arylhydroxylamines were identified as the sole intermediates. Nevertheless, the corresponding nitrosoarenes can also be formed as intermediates, which, however, are rapidly transformed into the desired arylamines in the presence of methylhydrazine through a noncatalytic path. On the basis of the observed high chemoselectivity and yields, and the fast and clean reaction processes, the present catalytic system [Co(kappa S,N-tfmp2S)(3)]/MeNHNH2 shows promise for the efficient synthesis of aromatic amines that could find various industrial applications.

About 1-(4-Nitrophenyl)ethanone, If you have any questions, you can contact Ioannou, DI; Gioftsidou, DK; Tsina, VE; Kallitsakis, MG; Hatzidimitriou, AG; Terzidis, MA; Angaridis, PA; Lykakis, IN or concate me.. COA of Formula: C8H7NO3

Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem

Computed Properties of C8H7NO3. In 2019.0 CHEM COMMUN published article about DYNAMIC CONTROL; HIGHLY EFFICIENT; SELF-ASSEMBLIES; SIDE-CHAINS; POLY(QUINOXALINE-2,3-DIYL)S; CHIRALITY; AMPLIFICATION; SYSTEMS; STEREOCONTROL; INVERSION in [Li, Yan; Caumes, Xavier; Raynal, Matthieu; Bouteiller, Laurent] Sorbonne Univ, CNRS, Inst Parisien Chim Mol, Equipe Chim Polymeres, 4 Pl Jussieu, F-75005 Paris, France in 2019.0, Cited 54.0. The Name is 1-(4-Nitrophenyl)ethanone. Through research, I have a further understanding and discovery of 100-19-6.

A multi-configurable catalyst, for which the degree of enantioinduction in successive reactions is varied between 6% ee and 52% ee, is achieved by supporting copper centres at the periphery of supramolecular helices. Precise characterization of the co-assemblies corroborates the relation between helix length and catalyst selectivity.

Computed Properties of C8H7NO3. About 1-(4-Nitrophenyl)ethanone, If you have any questions, you can contact Li, Y; Caumes, X; Raynal, M; Bouteiller, L or concate me.

Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem

Computed Properties of C8H7NO3. I found the field of Chemistry very interesting. Saw the article Synthesis, characterization, and catalytic activity of half-sandwich ruthenium complexes with pyridine/phenylene bridged NHC = E (NHC = N-heterocyclic carbene, E = S, Se) ligands published in 2020.0, Reprint Addresses Jia, WG; Du, J (corresponding author), Anhui Normal Univ, Coll Chem & Mat Sci, State Key Lab Cultivat Base,Minist Educ, Key Lab Funct Mol Solids,Anhui Lab Mol Based Mat, Wuhu 241002, Peoples R China.; Jia, WG (corresponding author), Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Peoples R China.. The CAS is 100-19-6. Through research, I have a further understanding and discovery of 1-(4-Nitrophenyl)ethanone.

Three half-sandwichruthenium(II) complexes with pyridine/phenylene bridged NHC = E (NHC = N-heterocyclic carbene, E = S, Se) ligands [Ru(p-cymene)L](PF6)(1-2) (1a-1c, L = ligand) were synthesized and characterized. All ruthenium complexes were fully characterized by H-1 and C-13 NMR spectra, mass spectrometry, and single-crystalX-ray diffraction methods. Moreover, the half-sandwich ruthenium complexes with NHC = E ligands showed highly catalytic activities towards to the tandem dehydrogenation of ammonia borane (AB) and hydrogenation of R-NO2 to R-NH2 at 353 K in water.

Computed Properties of C8H7NO3. About 1-(4-Nitrophenyl)ethanone, If you have any questions, you can contact Jia, WG; Du, TT; Gao, LL; Du, J or concate me.

Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem

Authors Zhang, LK; Wang, JM; Shang, NZ; Gao, ST; Gao, YJ; Wang, C in ELSEVIER published article about IN-SITU SYNTHESIS; DOPED CARBON; AMMONIA BORANE; SELECTIVE HYDROGENATION; GRAPHENE OXIDE; NITROARENE HYDROGENATION; AU NANOPARTICLES; CASCADE REACTION; DEHYDROGENATION; METAL in [Zhang, Longkang; Wang, Junmin; Shang, Ningzhao; Gao, Shutao; Wang, Chun] Hebei Agr Univ, Coll Sci, Baoding 071001, Peoples R China; [Gao, Yongjun] Univ Hebei, Coll Chem & Environm Sci, Baoding 071002, Peoples R China in 2019.0, Cited 52.0. Application In Synthesis of 1-(4-Nitrophenyl)ethanone. The Name is 1-(4-Nitrophenyl)ethanone. Through research, I have a further understanding and discovery of 100-19-6

A non-noble heterogeneous catalyst, ultra dispersed Co anchored on ordered porous nitrogen-riched carbon (CoN@PCN) was fabricated through a sacrificial-template pyrolysis strategy, in which SBA-15 and 1, 10-phenanthroline were employed as the hard template and ligand, respectively. Co was ultra dispersed owing to the confinement effect of SBA-15 and the strong coordination effect of Co with phenanthroline. The CoN@PCN displayed excellent catalytic activity and selectivity for the hydrogenation of nitroarenes with ammonia-borane as hydrogen donor under mild conditions, which can be ascribed to the ultra dispersed Co sites, high adsorption ability of the catalyst for ammonia-borane, large specific surface area and abundant porous structure of CoN@PCN. Based on the results of density functional theory calculations, the catalytic mechanism of CoN@PCN for the hydrogenation reaction was proposed. The recycled CoN@PCN had no obvious change in catalytic performance after five consecutive cycles, indicating its durability and recyclability.

Application In Synthesis of 1-(4-Nitrophenyl)ethanone. About 1-(4-Nitrophenyl)ethanone, If you have any questions, you can contact Zhang, LK; Wang, JM; Shang, NZ; Gao, ST; Gao, YJ; Wang, C or concate me.

Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem

An article Zinc Hydride-Catalyzed Hydrofuntionalization of Ketones WOS:000569376800017 published article about N-HETEROCYCLIC CARBENE; COMPLEXES SYNTHESIS; HYDROSILYLATION; HYDROBORATION; ALDEHYDES; REACTIVITY; REDUCTION; ALKYNES; IMINES in [Sahoo, Rajata Kumar; Mahato, Mamata; Nembenna, Sharanappa] Homi Bhabha Natl Inst HBNI, Natl Inst Sci Educ & Res NISER, Sch Chem Sci, Bhubaneswar 752050, Odisha, India; [Jana, Achintya] Indian Inst Sci, Undergrad Programme, Bangalore 560012, Karnataka, India in 2020.0, Cited 74.0. The Name is 1-(4-Nitrophenyl)ethanone. Through research, I have a further understanding and discovery of 100-19-6. Application In Synthesis of 1-(4-Nitrophenyl)ethanone

Three new dimeric bis-guanidinate zinc(II) alkyl, halide, and hydride complexes [LZnEt](2) (1), [LZnI](2) (2) and [LZnH](2) (3) were prepared. Compound 3 was successfully employed for the hydrosilylation and hydroboration of a vast number of ketones. The catalytic performance of 3 in the hydroboration of acetophenone exhibits a turnover frequency, reaching up to 5800 h(-)(1), outperforming that of reported zinc hydride catalysts. Notably, both intra- and intermolecular chemoselective hydrosilylation and hydroboration reactions have been investigated.

Application In Synthesis of 1-(4-Nitrophenyl)ethanone. About 1-(4-Nitrophenyl)ethanone, If you have any questions, you can contact Sahoo, RK; Mahato, M; Jana, A; Nembenna, S or concate me.

Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem

In 2020.0 RSC ADV published article about EFFICIENT CATALYST; SULFONIC-ACID; GAMMA-FE2O3 NANOPARTICLES; SULFURIC-ACID; ACETALIZATION; ACETALS; METHOXYMETHYLATION; ALDEHYDES; DITHIOACETALIZATION; HYDROLYSIS in [Khaef, Sepideh; Zolfigol, Mohammad Ali; Yarie, Meysam] Bu Ali Sina Univ, Dept Organ Chem, Fac Chem, Hamadan, Hamadan, Iran; [Khaef, Sepideh; Taherpour, Avat Arman] Razi Univ, Dept Organ Chem, Fac Chem, Kermanshah, Iran in 2020.0, Cited 92.0. The Name is 1-(4-Nitrophenyl)ethanone. Through research, I have a further understanding and discovery of 100-19-6. Quality Control of 1-(4-Nitrophenyl)ethanone

Protection techniques of functional groups within the structure of organic compounds are important synthetic methods against unwanted attacks from various reagents during synthetic sequences. Acetal and thioacetal groups are well known as protective functional groups in organic reactions. In this study, acetalization of carbonyl compounds with diols and dithiols and methoxymethylation of alcohols with formaldehyde dimethyl acetal (FDMA) have been carried out using sulfamic acid-functionalized magnetic Fe3O4 nanoparticles (SA-MNPs) as a heterogeneous solid acid catalyst. Products were characterized by FT-IR and NMR spectroscopies. The structural and electronic properties of some products were computed by quantum mechanical (QM) methods. Depending on the stereochemistry and electronic properties that were obtained by computational results, we have suggested that hyperconjugation plays a key role in the structural properties of 2-phenyl-1,3-dioxolane derivatives, and also the electron transfer between pi-electrons of the aromatic ring with the 3d orbital of S-atoms influences the 2-phenyl-1,3-dithiane derivatives’ structure.

Quality Control of 1-(4-Nitrophenyl)ethanone. About 1-(4-Nitrophenyl)ethanone, If you have any questions, you can contact Khaef, S; Zolfigol, MA; Taherpour, AA; Yarie, M or concate me.

Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem