Day: October 13, 2021

Authors Tseng, HC; Shen, CT; Matsumoto, K; Shih, DN; Liu, YH; Peng, SM; Yamaguchi, S; Lin, YF; Chiu, CW in AMER CHEMICAL SOC published article about CHEMISTRY; BORENIUM; CATION; BORINIUM; ION; REDUCTION; COMPLEXES; CATALYST; CHLORIDE; KETONES in [Tseng, Hsi-Ching; Shen, Chao-Tang; Shih, Ding-Nan; Liu, Yi-Hung; Peng, Shie-Ming; Chiu, Ching-Wen] Natl Taiwan Univ, Dept Chem, 1,Sect 4,Roosevelt Rd, Taipei 10617, Taiwan; [Matsumoto, Kentaro; Yamaguchi, Shigehiro] Nagoya Univ, Grad Sch Sci, Dept Chem, Chikusa Ku, Nagoya, Aichi 4648602, Japan; [Lin, Ya-Fan] Kaohsiung Med Univ, Dept Fragrance & Cosmet Sci, 100 Shi Chuan First Rd, Kaohsiung 80708, Taiwan in 2019.0, Cited 58.0. Recommanded Product: 100-19-6. The Name is 1-(4-Nitrophenyl)ethanone. Through research, I have a further understanding and discovery of 100-19-6

The chemistry of the boron cation has been revitalized in the past decade due to its newfound application in stoichiometric and catalytic organic reactions. To extend the frontier of boron cation catalysis, we came to discover that a mesityl-substituted eta(5)-Cp*-coordinated boron cation could serve as a powerful Lewis acid for organic catalytic transformations. The boron cation [Cp*B-Mes][B(C6F5)(4)] ([1] [B(C6F5)(4)]) stabilized in a boronium-like electronic structure binds to Et3PO readily and displays an acceptor number exceeding that of B(C6F5)(3) on the Gutmann-Beckett acidity scale. The steric and electronic stabilization exerted by the electron-donating Cp* renders the highly Lewis acidic boron cation an easy-to-handle catalyst for hydrodeoxygenation of aryl ketones at ambient temperature. The exceptional catalytic performance of [1](+) implies that the incorporation of a coordinatively flexible substituent at boron is critical in bringing catalytic activity and stability to boron cation catalysts.

Recommanded Product: 100-19-6. About 1-(4-Nitrophenyl)ethanone, If you have any questions, you can contact Tseng, HC; Shen, CT; Matsumoto, K; Shih, DN; Liu, YH; Peng, SM; Yamaguchi, S; Lin, YF; Chiu, CW or concate me.

Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem

I found the field of Chemistry very interesting. Saw the article Synthesis, characterization, and catalytic activity of half-sandwich ruthenium complexes with pyridine/phenylene bridged NHC = E (NHC = N-heterocyclic carbene, E = S, Se) ligands published in 2020.0. SDS of cas: 100-19-6, Reprint Addresses Jia, WG; Du, J (corresponding author), Anhui Normal Univ, Coll Chem & Mat Sci, State Key Lab Cultivat Base,Minist Educ, Key Lab Funct Mol Solids,Anhui Lab Mol Based Mat, Wuhu 241002, Peoples R China.; Jia, WG (corresponding author), Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Peoples R China.. The CAS is 100-19-6. Through research, I have a further understanding and discovery of 1-(4-Nitrophenyl)ethanone

Three half-sandwichruthenium(II) complexes with pyridine/phenylene bridged NHC = E (NHC = N-heterocyclic carbene, E = S, Se) ligands [Ru(p-cymene)L](PF6)(1-2) (1a-1c, L = ligand) were synthesized and characterized. All ruthenium complexes were fully characterized by H-1 and C-13 NMR spectra, mass spectrometry, and single-crystalX-ray diffraction methods. Moreover, the half-sandwich ruthenium complexes with NHC = E ligands showed highly catalytic activities towards to the tandem dehydrogenation of ammonia borane (AB) and hydrogenation of R-NO2 to R-NH2 at 353 K in water.

SDS of cas: 100-19-6. About 1-(4-Nitrophenyl)ethanone, If you have any questions, you can contact Jia, WG; Du, TT; Gao, LL; Du, J or concate me.

Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem

Swamy, PCA; Varenikov, A; de Ruiter, G in [Swamy, Chinna Ayya P.; Varenikov, Andrii; de Ruiter, Graham] Technion Israel Inst Technol, Schulich Fac Chem, IL-3200008 Haifa, Israel published Direct Asymmetric Hydrogenation and Dynamic Kinetic Resolution of Aryl Ketones Catalyzed by an Iridium-NHC Exhibiting High Enantio- and Diastereoselectivity in 2020.0, Cited 67.0. COA of Formula: C8H7NO3. The Name is 1-(4-Nitrophenyl)ethanone. Through research, I have a further understanding and discovery of 100-19-6.

A chiral iridium carbene-oxazoline catalyst is reported that is able to directly and efficiently hydrogenate a wide variety of ketones in excellent yields and good enantioselectivity (up to 93 % ee). Moreover, when using racemic alpha-substituted ketones, excellent diastereoselectivities were obtained (dr 99:1) by dynamic kinetic resolution of the in situ formed enolate. Overall, the herein described hydrogenation occurs under ambient conditions using low hydrogen pressures, providing a direct and atom efficient method towards chiral secondary alcohols.

COA of Formula: C8H7NO3. About 1-(4-Nitrophenyl)ethanone, If you have any questions, you can contact Swamy, PCA; Varenikov, A; de Ruiter, G or concate me.

Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem

I found the field of Chemistry very interesting. Saw the article Enantiopure Calcium Iminophosphonamide Complexes: Synthesis, Photoluminescence, and Catalysis published in 2021.0. HPLC of Formula: C8H7NO3, Reprint Addresses Roesky, PW (corresponding author), Karlsruhe Inst Technol KIT, Inst Inorgan Chem, Engesserstr 15, D-76131 Karlsruhe, Germany.. The CAS is 100-19-6. Through research, I have a further understanding and discovery of 1-(4-Nitrophenyl)ethanone

The synthesis of calcium complexes ligated by three different chiral iminophosphonamide ligands, L-H (L=[Ph2P{N(R)CH(CH3)Ph}(2)]), L ‘-H (L ‘=[Ph2P{NDipp}{N(R)CH(CH3)Ph}]), (Dipp=2,6-(Pr2C6H3)-Pr-i), and L ”-H (L ”=[Ph2P{N(R)CH(CH3)naph}(2)]), (naph=naphthyl) is presented. The resulting structures [L2Ca], [L ‘ Ca-2], and [L ” Ca-2] represent the first examples of enantiopure homoleptic calcium complexes based on this type of ligands. The calcium complexes show blue-green photoluminescence (PL) in the solid state, which is especially bright at low temperatures. Whereas the emission of [L ” Ca-2] is assigned to the fluorescence of naphthyl groups, the PL of [L2Ca] and [L ‘ Ca-2] is contributed by long-lived phosphorescence and thermally activated delayed fluorescence (TADF), with a strong variation of the PL lifetimes over the temperature range of 5-295 K. Furthermore, an excellent catalytic activity was found for these complexes in hydroboration of ketones at room temperature, although no enantioselectivity was achieved.

HPLC of Formula: C8H7NO3. About 1-(4-Nitrophenyl)ethanone, If you have any questions, you can contact Goswami, B; Feuerstein, TJ; Yadav, R; Koppe, R; Lebedkin, S; Kappes, MM; Roesky, PW or concate me.

Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem

Computed Properties of C8H7NO3. Authors Rai, P; Chettri, P; Kar, S; Nagar, MA; Srivastava, S; Golakoti, NR in SPRINGER INTERNATIONAL PUBLISHING AG published article about in [Rai, Prashant; Kar, Swayamsiddha; Golakoti, Nageswara Rao] Sri Sathya Sai Inst Higher Learning, Dept Chem, Prasanthinilayam 515134, Andhra Pradesh, India; [Chettri, Prajal; Nagar, Malhar Anupam; Srivastava, Shailesh] Sri Sathya Sai Inst Higher Learning, Dept Phys, Prasanthinilayam 515134, Andhra Pradesh, India in 2021, Cited 35. The Name is 1-(4-Nitrophenyl)ethanone. Through research, I have a further understanding and discovery of 100-19-6

Fifteen chalcone derivatives having D-A-D, D-A-A and A-A-D architectures have been synthesized by Claisen-Schmidt condensation reaction and characterized by UV-Vis, IR, H-1-NMR, C-13-NMR and Mass spectrometry. In order to unambiguously establish the structure-activity relationship for the non-linear optical activity of these compounds, for the first time to our knowledge, we use the femtosecond degenerate four wave mixing (DFWM) technique to quantify and compare the third-order non-linear optical (NLO) activity of all the 15 compounds, under identical conditions. The second harmonics generation (SHG) efficiencies for all the compounds have also been evaluated using the Kurtz-Perry powder method. Among the compounds that we have synthesized here, the ones with A-A-D architecture show the highest NLO activity. Our results show that the NLO activity of a compound with A-A-D architecture can be further enhanced by incorporating a substituent with strong electron withdrawing ability on ring A and strong electron donating substituent on ring B. The results of the in silico studies that we have carried out correlate well with our experimental findings. The compounds (E)-3-(4-(dimethylamino)phenyl)-1-(4-nitrophenyl)prop-2-en-1-one with the compound code (4-N(CH3)(2)-4 ‘-NO2) and (E)-3-(4-methoxyphenyl)-1-(4-nitrophenyl)prop-2-en-1-one with the compound code (4-MeO-4 ‘-NO2) show the highest NLO activity among the compounds we have reported here.

Computed Properties of C8H7NO3. About 1-(4-Nitrophenyl)ethanone, If you have any questions, you can contact Rai, P; Chettri, P; Kar, S; Nagar, MA; Srivastava, S; Golakoti, NR or concate me.

Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem

Quality Control of 1-(4-Nitrophenyl)ethanone. In 2021.0 INORG CHIM ACTA published article about X-RAY-STRUCTURE; DENSITY-FUNCTIONAL THEORY; IRIDIUM(III) COMPLEXES; EXCITATION-ENERGIES; CARBON-SULFUR; RECENT TOPICS; ELECTROCHEMISTRY; EFFICIENT; ACTIVATION; APPROXIMATION in [Biswas, Sujan; Manna, Chandan Kumar; Naskar, Rahul; Das, Akash; Mondal, Tapan Kumar] Jadavpur Univ, Inorgan Chem Sect, Dept Chem, Kolkata 700032, India in 2021.0, Cited 59.0. The Name is 1-(4-Nitrophenyl)ethanone. Through research, I have a further understanding and discovery of 100-19-6.

A new rhodium(III)-triphenylphosphine mixed ligand complex, [Rh(PPh3)(L)Cl-2] (1) is synthesized by benzylic C-S bond cleavage of L-CH2Ph ligand (where, L-CH2Ph = 2-(benzylthio)-N-(pyridin-2-ylmethylene)aniline). The complex is thoroughly characterized by several spectroscopic techniques. Geometry of the complex is confirmed by single crystal X-ray crystallography. Electronic structure, redox properties, absorption and emission properties of the complex were studied. DFT and TDDFT calculations were carried out to interpret the electronic structure and absorption properties of the complex respectively. The synthesized Rh(III) complex was tested as catalyst towards transfer hydrogenation reaction of ketones in iPrOH and an excellent catalytic conversion was observed under mild conditions.

Quality Control of 1-(4-Nitrophenyl)ethanone. About 1-(4-Nitrophenyl)ethanone, If you have any questions, you can contact Biswas, S; Manna, CK; Naskar, R; Das, A; Mondal, TK or concate me.

Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem

Authors Babon, JC; Esteruelas, MA; Lopez, AM; Onate, E in AMER CHEMICAL SOC published article about H BOND ACTIVATION; SELECTIVE CATALYTIC-HYDROGENATION; HEXAHYDRIDE COMPLEX; LIGANDS PREPARATION; N-H; DEHYDROGENATION; HYDRIDE; VINYLIDENE; RUTHENIUM; REACTIVITY in [Babon, Juan C.; Esteruelas, Miguel A.; Lopez, Ana M.; Onate, Enrique] Univ Zaragoza CSIC, Dept Quim Inorgan, Inst Sintesis Quim & Catalisis Homogenea ISQCH, Ctr Innovac Quim Avanzada ORFEO CINQA, Zaragoza 50009, Spain in 2020, Cited 116. Product Details of 86-29-3. The Name is 2,2-Diphenylacetonitrile. Through research, I have a further understanding and discovery of 86-29-3

The transformation of alkyl nitriles to symmetrical and asymmetrical secondary aliphatic amines promoted by the hexahydride complex OsH6 ((PPr3)-Pr-i)(2) (1) is described, and the mechanisms of the reactions involved are established. Complex 1 catalyzes the aforementioned transformations of aryl-, pyridyl-, and alkoxy-functionalized alkyl nitriles with linear or branched chains. The formation of the secondary amines involves primary imines, primary amines, and secondary imines as organic intermediates. The reactions take place under mild conditions (toluene, 100 degrees C, and 4 bar of H-2). Stoichiometric reactions of 1 with pivalonitrile and 2-methoxyacetonitrile have allowed us to isolate the trihydride azavinylidene derivatives OsH3{=N=CHR}((PPr3)-Pr-i)(2) (R = Bu-t (3), CH2OMe (4)). Their formation involves the insertion of the N-C triple bond of the substrates into an Os-H bond of the unsaturated tetrahydride OsH4 ((PPr3)-Pr-i)(2) (A), which is generated by reductive elimination of H-2 from the hexahydride precursor. The reaction of these trihydride azavinylidene species with H-2 is the key step for the reduction of the N-C triple bond of the nitriles. In the absence of H-2, the attack of A to the azavinylidene ligand produces the rupture of its C(sp(2))-C(sp(3)) bond. As a consequence of this attack and the presence of primary imines and amines in the reaction media, the binuclear complexes ((PPr3)-Pr-i)(2) H4Os(mu-CN)OsH3{kappa(1)-N-(NH= CHCH2OMe)}((PPr3)-Pr-i)(2) (5) and ((PPr3)-Pr-i)(2)H4Os(mu-CN)OsH3{kappa(1)-N-(NH2CH2CH2OMe)}((PPr3)-Pr-i)(2) (6) have been isolated and characterized by X-ray diffraction analysis, for 2-methoxyacetonitrile. DFT calculations reveal noticeable similarities between the hydrogenations of nitriles to primary imines and those of primary imines to primary amines.

About 2,2-Diphenylacetonitrile, If you have any questions, you can contact Babon, JC; Esteruelas, MA; Lopez, AM; Onate, E or concate me.. Product Details of 86-29-3

Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem

An article Metal-Free Oxidative Esterification of Ketones and Potassium Xanthates: Selective Synthesis of alpha-Ketoesters and Esters WOS:000607535100009 published article about CARBON BOND-CLEAVAGE; CATALYZED ESTERIFICATION; CHEMOSELECTIVE SYNTHESIS; MEDIATED ADDITION; AEROBIC OXIDATION; ALCOHOLS; ACETOPHENONES; OXYGENATION; INHIBITORS; KETOAMIDES in [Luo, Xianglin; He, Runfa; Liu, Qiang; Gao, Yanping; Li, Jingqing; Chen, Xiuwen; Zhu, Zhongzhi; Huang, Yubing; Li, Yibiao] Wuyi Univ, Sch Biotechnol & Hlth Sci, Jiangmen 529090, Guangdong, Peoples R China; [Liu, Qiang] Tsinghua Univ, Ctr Basic Mol Sci, Dept Chem, Beijing 100084, Peoples R China in 2020, Cited 74. COA of Formula: C8H7NO3. The Name is 1-(4-Nitrophenyl)ethanone. Through research, I have a further understanding and discovery of 100-19-6

A novel and efficient oxidative esterification for the selective synthesis of alpha-ketoesters and esters has been developed under metal-free conditions. In the protocol, various alpha-ketoesters and esters are available in high yields from commercially available ketones and potassium xanthates. Mechanistic studies have proven that potassium xanthate not only promotes oxidative esterification but also provides an alkoxy moiety for the reaction, which involves the cleavage and reconstruction of C-O bonds.

COA of Formula: C8H7NO3. About 1-(4-Nitrophenyl)ethanone, If you have any questions, you can contact Luo, XL; He, RF; Liu, Q; Gao, YP; Li, JQ; Chen, XW; Zhu, ZZ; Huang, YB; Li, YB or concate me.

Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem

An article Biomass-derived carbon-supported Ni catalyst: an effective heterogeneous non-noble metal catalyst for the hydrogenation of nitro compounds WOS:000507993700002 published article about CHEMOSELECTIVE HYDROGENATION; SELECTIVE HYDROGENATION; PD NANOPARTICLES; NITROARENES; REDUCTION; PATHWAY in [Tang, Qingjie; Yuan, Ziliang; Jin, Shiwei; Yao, Kaiyue; Yang, Hanmin; Chi, Quan; Liu, Bing] South Cent Univ Nationalities, Minist Educ, Key Lab Catalysis & Mat Sci, Wuhan 430074, Peoples R China in 2020.0, Cited 29.0. Name: 1-(4-Nitrophenyl)ethanone. The Name is 1-(4-Nitrophenyl)ethanone. Through research, I have a further understanding and discovery of 100-19-6

There has been a great deal of attention to the development of heterogeneous non-noble metal catalysts for the selective and mild hydrogenation of nitro compounds into primary amines. Herein, a biomass-derived carbon material supported Ni catalyst (Ni/C) was facilely prepared by a one-pot pyrolysis process, and the as-prepared Ni/C catalyst demonstrated a high catalytic activity for the hydrogenation of nitro compounds into primary amines at room temperature. The Ni/C catalyst not only demonstrated a high catalytic activity but also showed a good tolerance to other functional groups. Structurally diverse primary amines were achieved in yields from 92% to 99% within a few hours at room temperature under 5 bar H-2. Furthermore, the Ni/C catalyst showed good reusability without the loss of its activity.

Name: 1-(4-Nitrophenyl)ethanone. About 1-(4-Nitrophenyl)ethanone, If you have any questions, you can contact Tang, QJ; Yuan, ZL; Jin, SW; Yao, KY; Yang, HM; Chi, Q; Liu, B or concate me.

Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem

Gonzalez-Munoz, D; Casado-Sanchez, A; del Hierro, I; Gomez-Ruiz, S; Cabrera, S; Aleman, J in [Gonzalez-Munoz, Daniel; Casado-Sanchez, Antonio; Aleman, Jose] Univ Autonoma Madrid, Sci Fac, Organ Chem Dept, E-28049 Madrid, Spain; [del Hierro, Isabel; Gomez-Ruiz, Santiago] Univ Rey Juan Carlos, Escuela Super Ciencias Expt & Tecnol, Dept Biol & Geol Fis & Quim Inorgan, Madrid 28933, Spain; [Cabrera, Silvia] Univ Autonoma Madrid, Sci Fac, Inorgan Chem Dept, E-28049 Madrid, Spain; [Cabrera, Silvia; Aleman, Jose] Univ Autonoma Madrid, Inst Adv Res Chem Sci IAdChem, E-28049 Madrid, Spain published Size-selective mesoporous silica-based Pt(II) complex as efficient and reusable photocatalytic material in 2019.0, Cited 43.0. HPLC of Formula: C8H7NO3. The Name is 1-(4-Nitrophenyl)ethanone. Through research, I have a further understanding and discovery of 100-19-6.

The grafting of a Pt(II) photocatalyst into three different mesoporous silica-based materials with different particle sizes and pore sizes was easily achieved through an amide bond formation. The analysis and results of the different characterization techniques showed that the catalyst is immobilized inside the pores of the materials and the photophysical properties of the catalyst are preserved after the covalent anchoring. The photocatalytic material catalyzed efficiently the debromination reaction of different substrates and is reused without detriment in its catalytic activity. In addition, the incorporation of the catalyst into mesoporous silica materials with different pore size allows the selective debromination of substrates by size discrimination. (C) 2019 Elsevier Inc. All rights reserved.

HPLC of Formula: C8H7NO3. About 1-(4-Nitrophenyl)ethanone, If you have any questions, you can contact Gonzalez-Munoz, D; Casado-Sanchez, A; del Hierro, I; Gomez-Ruiz, S; Cabrera, S; Aleman, J or concate me.

Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem